Chiroptical sensing of citronellal: systematic development of a stereodynamic probe using the concept of isostericity.

Chiroptical sensing of citronellal: systematic development of a stereodynamic probe using the concept of isostericity.

Chemical communications (Cambridge, England) (2012-10-16)

Daniel P Iwaniuk, Christian Wolf

RESUMEN

A rationally designed stereodynamic ICD probe carrying two terminal amino functions for chemo- and enantioselective sensing of citronellal is introduced. The sensor shows strong Cotton effects upon diimine formation which can be used for accurate ee determination.

MATERIALES

Referencia del producto

Marca

Descripción del producto

27470

Sigma-Aldrich

(±)-Citronellal, ≥95.0% (GC)

343641

Sigma-Aldrich

(R)-(+)-Citronellal, technical grade

373753

Sigma-Aldrich

(S)-(−)-Citronellal, 96%

W230715

Sigma-Aldrich

(±)-Citronellal, natural, ≥85%, FCC, FG

72638

Supelco

(±)-Citronellal, analytical standard