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Merck

In situ electrogeneration of o-benzoquinone and high yield reaction with benzenethiols in a microflow system.

Chemical communications (Cambridge, England) (2012-02-04)
Tsuneo Kashiwagi, Fumihiro Amemiya, Toshio Fuchigami, Mahito Atobe
RESUMEN

We have successfully demonstrated that a microflow reactor is extremely useful in controlling reactions involving an unstable o-benzoquinone. The key features of the method are an effective o-benzoquinone generation and its rapid use for the following reaction without decomposition in a microflow system.

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Sigma-Aldrich
Thiophenol, 97%
Sigma-Aldrich
Thiophenol, ≥99%
Sigma-Aldrich
Sodium thiophenolate, technical grade, 90%
Supelco
Thiophenol, analytical standard