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  • Ultrasound promoted C-C bond formation: Heck reaction at ambient conditions in room temperature ionic liquids.

Ultrasound promoted C-C bond formation: Heck reaction at ambient conditions in room temperature ionic liquids.

Chemical communications (Cambridge, England) (2002-09-21)
R R Deshmukh, R Rajagopal, K V Srinivasan
ABSTRACT

Heck reaction proceeds at ambient temperature (30 degrees C) with considerably enhanced reaction rate (1.5-3 h) through the formation of Pd-biscarbene complexes and stabilized clusters of zero-valent Pd nanoparticles in ionic liquids under ultrasonic irradiation.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Sodium acetate, anhydrous, ReagentPlus®, ≥99.0%