14765
Thallium(I) acetate
purum, ≥97.0%
Synonym(s):
TlOAc, Acetic acid thallium(I) salt
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About This Item
Linear Formula:
CH3COOTl
CAS Number:
Molecular Weight:
263.43
Beilstein:
3693914
EC Number:
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
grade
purum
Quality Level
Assay
≥97.0%
form
solid
reaction suitability
core: thallium
reagent type: catalyst
SMILES string
CC(=O)O[Tl]
InChI
1S/C2H4O2.Tl/c1-2(3)4;/h1H3,(H,3,4);/q;+1/p-1
InChI key
HQOJMTATBXYHNR-UHFFFAOYSA-M
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General description
Thallium (I) acetate functions as a catalyst to enhance the rate of chemical reactions in the synthesis of isothiocyanates from isocyanides and disulfides. In addition, it is also used as the source of thallium ions in organic solvents for electrochemical reactions.
Application
- Thallium Use: An Overview: Offers a comprehensive overview of Thallium(I) acetate′s use in organic synthesis in the oxidation of olefins and hydrocarbons, and in epoxidation and polymerization reactions (Genchi et al., 2021).
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - STOT RE 2
Storage Class Code
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Electrochemical Behavior of Thallium Ion in Organic Solvents and its Application to Organic Synthesis
Tanabe T, et al.
ECS Transactions, 13(20), 7-7 (2008)
The thallium (I) salt-catalyzed formation of isothiocyanates from isocyanides and disulfides
Tanaka S, et al.
Bulletin of the Chemical Society of Japan, 50(10), 2785-2788 (1977)
Thies, R.W.; Boop, J. L. et al
The Journal of Organic Chemistry, 48, 2021-2021 (1983)
Grigg, R.; Kennewell, P. et al
Tetrahedron Letters, 33, 7789-7789 (1992)
The action of thallium acetate on spontaneous transmitter release in the rat neuromuscular junction.
H Wiegand et al.
Archives of toxicology, 55(4), 253-257 (1984-10-01)
Frequencies and amplitudes of miniature endplate potentials (MEPP's) were recorded from neuromuscular junctions of the rat phrenic nerve-diaphragm preparation in vitro. Superfusion of the preparations with Ringer solution containing thallium acetate (Tlac) gradually increased the frequency of MEPP's by a
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