sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

Natural product reports (2014-02-28)

Egor Geist, Andreas Kirschning, Thomas Schmidt

ABSTRACT

This Highlight covers the current status of relatively unexplored sp(3)-sp(3) cross-coupling reactions with particular focus on natural product and related syntheses.

MATERIALS

Product Number

Brand

Product Description

577995

Sigma-Aldrich

Nickel, nanopowder, <100 nm avg. part. size, ≥99% trace metals basis

GF75580421

Nickel, foil, 4mm disks, thickness 0.125mm, annealed, 99%

GF28868439

Nickel, foil, 50mm disks, thickness 0.005mm, as rolled, 99.9%

GF34210820

Nickel, foil, 50mm disks, thickness 0.025mm, 99.9%

GF32204775

Nickel, foil, 10mm disks, thickness 0.05mm, as rolled, 99.99+%

GF44280974

Nickel, rod, 200mm, diameter 40mm, 99%

GF70332870

Nickel, rod, 100mm, diameter 3.3mm, 99.99+%

GF34661774

Nickel, foil, 25mm disks, thickness 0.0125mm, annealed, 99%

GF33231675

Nickel, wire reel, 5m, diameter 0.025mm, as drawn, 99.98%

GF62726597

Nickel, foil, 6mm disks, thickness 0.005mm, as rolled, 99.9%

GF61528406

Nickel, wire reel, 50m, diameter 0.125mm, hard, 99.98%

GF33022381

Nickel, wire reel, 5m, diameter 0.0125mm, Stress relieved, 99.98%

GF52348608

Nickel, wire reel, 50m, diameter 0.125mm, annealed, 99.98%

GF88108623

Nickel, wire reel, 500m, diameter 0.15mm, as drawn, 99%

GF54123476

Nickel, wire reel, 500m, diameter 0.125mm, hard, 99.98%

GF07573989

Nickel, wire reel, 5m, diameter 2.0mm, hard, 99.98%

GF39346038

Nickel, foil, 6mm disks, thickness 0.015mm, 99.9%

GF07174762

Nickel, foil, 6mm disks, thickness 0.05mm, annealed, 99%

GF50019937

Nickel, foil, 6mm disks, thickness 0.009mm, 99.95%

GF71613828

Nickel, foil, 6mm disks, thickness 0.025mm, 99.9%

GF91030306

Nickel, foil, 6mm disks, thickness 0.25mm, annealed, 99%

GF26956413

Nickel, foil, 6mm disks, thickness 0.5mm, as rolled, 99.99+%

GF19962535

Nickel, foil, 50mm disks, thickness 0.0075mm, 99.9%

GF87509997

Nickel, foil, 4mm disks, thickness 0.5mm, annealed, 99.98%

GF82156912

Nickel, rod, 100mm, diameter 12.0mm, 99%

GF99799968

Nickel, rod, 100mm, diameter 30mm, 99%

GF49774034

Nickel, rod, 200mm, diameter 12.7mm, 99.98%

GF77026237

Nickel, foil, 15mm disks, thickness 0.008mm, 99.95%

GF17475903

Nickel, rod, 200mm, diameter 6.35mm, 99%

GF84978950

Nickel, foil, 10mm disks, thickness 0.25mm, as rolled, 99.99+%