- First kinetic evidence for the CH/π and π/π solute-solvent interaction of C60 in the Diels-Alder reaction with cyclohexadiene.
First kinetic evidence for the CH/π and π/π solute-solvent interaction of C60 in the Diels-Alder reaction with cyclohexadiene.
Organic & biomolecular chemistry (2012-01-13)
Takumi Oshima, Tsubasa Mikie, Naohiko Ikuma, Hajime Yakuma
PMID22237916
RESUMEN
The first CH/π solute-solvent interaction of C(60) was evidenced by the kinetic solvent effects in the Diels-Alder reaction with 1,3-cyclohexadiene based on the evaluation of linear free energy relationship of log k(2) with empirical solvent polarity and basicity parameters, E(T)(30) and D(π), respectively.
MATERIALES
Referencia del producto
Marca
Descripción del producto