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Merck
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Key Documents

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W354805

Sigma-Aldrich

2′-Hydroxyacetophenone

≥98%

Sinónimos:

2-Acetylphenol

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About This Item

Fórmula lineal:
HOC6H4COCH3
Número de CAS:
118-93-4
Peso molecular:
136.15
FEMA Number:
3548
Beilstein/REAXYS Number:
386123
EC Number:
204-288-0
Council of Europe no.:
4136
MDL number:
MFCD00002219
UNSPSC Code:
12164502
PubChem Substance ID:
24901776
Flavis number:
7.124
NACRES:
NA.21

biological source

synthetic

grade

Fragrance grade

agency

follows IFRA guidelines
meets purity specifications of JECFA

reg. compliance

EU Regulation 1223/2009

vapor density

4.7 (vs air)

vapor pressure

~0.2 mmHg ( 20 °C)

assay

≥98%

refractive index

n20/D 1.558 (lit.)

bp

213 °C/717 mmHg (lit.)

mp

3-6 °C (lit.)

density

1.133 g/mL at 20 °C
1.131 g/mL at 25 °C (lit.)

application(s)

flavors and fragrances

documentation

see Safety & Documentation for available documents

food allergen

no known allergens

fragrance allergen

no known allergens

organoleptic

hawthorne; herbaceous; phenolic; sweet

SMILES string

CC(=O)c1ccccc1O

InChI

1S/C8H8O2/c1-6(9)7-4-2-3-5-8(7)10/h2-5,10H,1H3

InChI key

JECYUBVRTQDVAT-UHFFFAOYSA-N

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Storage Class

10 - Combustible liquids

wgk_germany

WGK 2

flash_point_f

222.8 °F - closed cup

flash_point_c

106 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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R R Zaky et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 81(1), 28-34 (2011-07-26)
Schiff base complexes of Cu(II), Ni(II) and Zn(II) with the o-hydroxyacetophenone [N-(3-hydroxy-2-naphthoyl)] hydrazone (H(2)o-HAHNH) containing N and O donor sites have been synthesized. Both ligand and its metal complexes were characterized by different physicochemical methods, elemental analysis, molar conductivity ((1)H
R R Zaky et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 97, 683-694 (2012-08-14)
The o-Hydroxy acetophenone [N-(3-hydroxy-2-naphthoyl)] hydrazone (H(2)o-HAHNH) has been prepared and its structure is confirmed by elemental analysis, IR, (1)H NMR and (13)C NMR spectroscopy. It has been used to produce diverse complexes with Co(II), Cd(II), Hg(II) and U(VI)O(2) ions. The
Shuai Chen et al.
Organic letters, 14(11), 2806-2809 (2012-05-17)
Flavin catalysts perform the first organocatalytic Dakin oxidation of electron-rich arylaldehydes to phenols under mild, basic conditions. Catechols are readily prepared, and the oxidation of 2-hydroxyacetophenone was achieved. Aerobic oxidation is displayed in the presence of Zn(0) as a reducing
Subramanya Gupta Sreerama et al.
Inorganic chemistry, 44(18), 6299-6307 (2005-08-30)
A series of dinuclear complexes of Mn(III), Fe(III), and Co(III) with two diazine Schiff bases, H2salhn and H2mesalhn, is reported. The Schiff bases are prepared by condensation reactions of hydrazine with salicylaldehyde (H2salhn) and with 2-hydroxyacetophenone (H2mesalhn) in 1:2 mol
Sheng-Li Liu et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 69(2), 664-669 (2007-07-24)
Novel europium (III) complexes of the formulae Eu(OHAP)(3).2H2O, Eu(OHAP)(3)Phen, Eu2(DAR)(3).4H2O and Eu2(DAR)(3)Phen2 (HOHAP=2'-hydroxyacetophenone, H2DAR=4,6-diacetylresorcinol, Phen=1,10-phenanthroline) have been designed and synthesized in this paper. These complexes were characterized by elemental analysis, FT-IR, and UV-vis. Based on these observations, the ligands are
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