905917

(Ir[Me(Me)ppy]₂(dtbpy))PF₆

• Sinónimos: 4,4′-Bis(t-butyl-2,2′-bipyridine]bis[5-methyl-2-(4-methyl-2-pyridinyl-kN)phenyl-kC]iridium hexafluorophosphate, Ir(dmppy)₂(dtbbpy)PF₆
• Fórmula empírica (notación de Hill): C₄₄H₄₈F₆IrN₄P
• Número de CAS: 1607469-49-7
• Peso molecular: 970.06
• UNSPSC Code: 12161600
• NACRES: NA.22

Propiedades

• form: powder
• reaction suitability: core: iridium; reagent type: catalyst; reaction type: Photocatalysis
• photocatalyst activation: 465 nm
• SMILES string: F[P-](F)(F)(F)(F)F.CC1=CC([Ir+]([N]2=C3C=C(C)C=C2)(C4=C5C=CC(C)=C4)([N]6=C7C=C(C(C)(C)C)C=C6)([N]8=C7C=C(C(C)(C)C)C=C8)[N]9=C5C=C(C)C=C9)=C3C=C1

Descripción

Application

(Ir[Me(Me)ppy]₂(dtbpy))PF₆ or Ir(dmppy)₂(dtbbpy)PF₆ is an iridium photoredox catalyst that facilitates a variety of transformations using visible light, including the α- and β-alkylation of aldehydes.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Direct β-Alkylation of Aldehydes via Photoredox Organocatalysis

Direct, enantioselective α-alkylation of aldehydes using simple olefins

Información de seguridad

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable