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Merck

698687

Sigma-Aldrich

Poly[(9,9-di-n-octylfluorenyl-2,7-diyl)-alt-(benzo[2,1,3]thiadiazol-4,8-diyl)]

average Mn ≤25000

Sinónimos:

F8BT

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About This Item

Fórmula lineal:
(C35H42N2S)n
Número de CAS:
UNSPSC Code:
12352103
NACRES:
NA.23

form

powder

mol wt

average Mn ≤25000

solubility

THF: soluble
chloroform: soluble

fluorescence

λex 447 nm; λem 530-560 nm in chloroform

Mw/Mn

<3

semiconductor properties

P-type (mobility=4×10−3 cm2/V·s)

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General description

F8BT is a fluorene copolymer that is used as a light-emitting polymer (LEP) with low energy of lowest unoccupied molecular orbital (LUMO), high electron mobility and luminance.

Application

F8BT can be used with poly(9,9-di-n-octylfluorenyl-2,7-diyl) (PTO) to map the effect of noise sources on photoconducting charge transports by evaluating the conductivity and noise source density (Nt). It may also form a nanocomposite with single walled carbon nanotube (SWCNT) with excellent electric properties and high Seebeck coefficient, for potential application in the development of photovoltaic power and biomass energy. Organic light emitting diode (OLED) devices can be fabricated by depositing a blend of F8 and F8BT on PEDOT:PSS films.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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Morphology-dependent trap formation in bulk heterojunction photodiodes
Shao G, et al.
The Journal of Physical Chemistry B, 117(16), 4654-4660 (2013)
Surface, interface and electronic properties of F8: F8BT polymeric thin films used for organic light-emitting diode applications
Borges BG, et al.
Polymer International, 67(6), 691-699 (2018)
Enhanced figure of merit of poly (9, 9-di-n-octylfluorene-alt-benzothiadiazole) and SWCNT thermoelectric composites by doping with FeCl3
Zhou X, et al.
Journal of Applied Polymer Science, 16(3), 47011-47011 (2018)
Efficient polymer light-emitting diode using air-stable metal oxides as electrodes
Bolink HJ, et al.
Advanced Materials, 21(1), 79-82 (2009)
He, Y.; Gong, S.; Hattori, R.; Kanicki,J.
Applied Physics Letters, 74, 2265-2265 (1999)

Artículos

The development of high-performance conjugated organic molecules and polymers has received widespread attention in industrial and academic research.

Since their discovery, organic light emitting devices (OLEDs) have evolved from a scientific curiosity into a technology with applications in flat panel displays and the potential to revolutionize the lighting market. During their relatively short history, the technology has rapidly advanced, and device efficiencies have increased more than 20-fold, approaching the theoretical limit for internal quantum efficiencies.

Organic photovoltaics (OPVs) represent a low-cost, lightweight, and scalable alternative to conventional solar cells. While significant progress has been made in the development of conventional bulk heterojunction cells, new approaches are required to achieve the performance and stability necessary to enable commercially successful OPVs.

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