394467

Morpholine

purified by redistillation, ≥99.5%

• Sinónimos: Tetrahydro-1,4-oxazine
• Fórmula empírica (notación de Hill): C₄H₉NO
• Número de CAS: 110-91-8
• Peso molecular: 87.12
• Beilstein: 102549
• Número CE: 203-815-1
• Número MDL: MFCD00005972
• Código UNSPSC: 12352100
• ID de la sustancia en PubChem: 24864597
• NACRES: NA.22

Propiedades

• densidad de vapor: 3 (vs air)
• Nivel de calidad: 200
• presión de vapor: 31 mmHg ( 38 °C); 7 mmHg ( 20 °C)
• Ensayo: ≥99.5%
• Formulario: liquid
• temp. de autoignición: 590 °F
• purificado por: redistillation
• lim. expl.: 10.8 %
• índice de refracción: n20/D 1.454 (lit.)
• bp: 129 °C (lit.); 129 °C
• mp: −7-−5 °C (lit.)
• solubilidad: water: miscible
• densidad: 0.996 g/mL at 25 °C (lit.)
• grupo funcional: ether
• cadena SMILES: C1COCCN1
• InChI: 1S/C4H9NO/c1-3-6-4-2-5-1/h5H,1-4H2
• Clave InChI: YNAVUWVOSKDBBP-UHFFFAOYSA-N

Descripción

Descripción general

Morpholine is a heterocyclic secondary amine. It is formed by the condensation of diethanolamine and sulfuric acid. Its IR spectra and Raman spectra at -180°C has been recorded. The crystal structure of morpholine has been determined at 150K. The microwave spectra of morpholine within the 8 to 40GHz region have been investigated. Ascorbate anion and glutathione have been reported to inhibit the aqueous reaction between nitrogen dioxide and morpholine. Conformational studies by Raman spectroscopy and theoretical calculations suggest that equatorial chair conformation of morpholine predominates in the pure liquid state. Degradation of morpholine using Mycobacterium sp. strain RP1 has been proposed.

Aplicación

Morpholine is suitable for use as a test compound in the study of morpholine biodegradation by Mycobacterium strains.
It may be used in the following studies:

• As a reactant in the synthesis of 1,3-dihydro-1-hydroxy-3-morpholin-4-yl-2,1-benzoxaborole by reacting with o-formylphenylboronic acid.
• As a corrosion inhibitor and to maintain basic pH in boiler feed water.
• As a reactant in the bis(β-ketoenolates)nickel(II) adducts of morpholine.
• As one of the reagent used in the colorimetric quantitative determination of C-2 unsubstituted phenothiazine derivatives.
• As a reactant in the quantitative determination of α,β-unsaturated compounds.

Información de seguridad

• Pictogramas: GHS02,GHS06,GHS08,GHS05
• Palabra de señalización: Danger
• Frases de peligro: H226,H302,H311 + H331,H314,H361fd
• Consejos de prudencia: P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Clasificaciones de peligro: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Repr. 2 - Skin Corr. 1B
• Código de clase de almacenamiento: 3 - Flammable liquids
• Clase de riesgo para el agua (WGK): WGK 1
• Punto de inflamabilidad (°F): 87.8 °F - closed cup
• Punto de inflamabilidad (°C): 31 °C - closed cup
• Equipo de protección personal: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter