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103543

Sigma-Aldrich

4-Nitroanisole

97%

Sinónimos:

1-Methoxy-4-nitrobenzene

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About This Item

Fórmula lineal:
O2NC6H4OCH3
Número de CAS:
100-17-4
Peso molecular:
153.14
Beilstein/REAXYS Number:
1865361
EC Number:
202-825-3
MDL number:
MFCD00007327
UNSPSC Code:
12352100
eCl@ss:
39032065
PubChem Substance ID:
24846610
NACRES:
NA.22

assay

97%

form

solid

density

1.233 g/mL at 25 °C (lit.)

SMILES string

COc1ccc(cc1)[N+]([O-])=O

InChI

1S/C7H7NO3/c1-11-7-4-2-6(3-5-7)8(9)10/h2-5H,1H3

InChI key

BNUHAJGCKIQFGE-UHFFFAOYSA-N

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Categorías relacionadas

General description

4-Nitroanisole undergoes photochemical nucleophilic aromatic substitution by hydroxide ion to form 4-methoxyphenol and 4-nitrophenol.

Application

4-Nitroanisole was used as probe to determine Π* of Kamlet-Taft solvent parameters and high pressure and supercritical water in the temperature range of 16-420 °C. 4-Nitroanisole was used as carbon and energy supplement for the isolation of Rhodococcus strains.

Biochem/physiol Actions

4-Nitroanisole is O-demethylated to 4-nitrophenol by human liver microsomes.

pictograms

Health hazard
GHS08

signalword

Warning

hcodes

H351,H412

Hazard Classifications

Aquatic Chronic 3 - Carc. 2

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 1

flash_point_f

266.0 °F - closed cup

flash_point_c

130 °C - closed cup

ppe

Eyeshields, Gloves

Certificados de análisis (COA)

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Vadim Samoilov et al.
Molecules (Basel, Switzerland), 25(7) (2020-04-15)
In this study approaches for chemical conversions of the renewable compounds 1,2-propanediol (1,2-PD) and 2,3-butanediol (2,3-BD) that yield the corresponding cyclic ketals and glycol ethers have been investigated experimentally. The characterization of the obtained products as potential green solvents and
H V Gelboin et al.
Chemical research in toxicology, 9(6), 1023-1030 (1996-09-01)
A panel of 17 hybridomas producing (MAbs) against human cytochrome P450 2E1 (h2E1) was generated by immunizing mice with baculovirus-expressed h2E1. All 17 hybridoma clones gave positive ELISA or immunoblots with either baculovirus-or vaccinia virus-expressed h2E1. Two of the latter
Song Chen et al.
Journal of economic entomology, 98(3), 943-946 (2005-07-19)
Cytochrome P450 monooxygenases are a major metabolic mechanism responsible for pyrethroid resistance in Helicoverpa armigera (Hübner) from Asia. Cytochrome P450-mediated O-demethylation activity toward p-nitroanisole (PNOD) of individual fourth instars was determined in five strains of H. armigera by using a
S F Simoni et al.
Journal of contaminant hydrology, 50(1-2), 99-120 (2001-07-28)
Microbial degradation rates in the subsurface are not only limited by the physiological capacity of the organisms, but also by inefficient supply of nutrients to the microbes. Although mass transfer limitation of biodegradation in the subsurface has been postulated for
V V Shumyantseva et al.
Biochemistry and molecular biology international, 45(1), 171-179 (1998-06-23)
Semisynthetic flavocytochromes, obtained by covalent binding of riboflavin with cytochromes P450 2B4, were able to catalyze the H2O2-mediated reactions of aniline p-hydroxylation, aminopyrine N-demethylation and p-nitroanizole' O-dealkylation. The rates of the flavocytochrome-catalyzed, H2O2-supported reactions far exceeded those of the appropriate
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