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The lone-pair-electron-driven phase transition and order-disorder processes in thermochromic (2-MIm)SbI

Dalton transactions (Cambridge, England : 2003) (2017-11-23)
A Gągor, G Banach, M Węcławik, A Piecha-Bisiorek, R Jakubas
RÉSUMÉ

The easy to prepare and stable in air (2-methylimidazolium) tetraiodoantimoniate(iii) single-crystals with optical band gap of 2.17(1) eV at room temperature have been synthesized. The crystal structure features one-dimensional [SbI

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Antimony(III) iodide, 98%