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Key Documents

939064

Sigma-Aldrich

Lithium hydroxide ChemBeads

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Synonyme(s) :

LiOH ChemBeads

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About This Item

Formule empirique (notation de Hill):
LiHO
Numéro CAS:
Poids moléculaire :
23.95
Numéro MDL:
Code UNSPSC :
12352100

Description

Reagent Type: Inorganic salt

Niveau de qualité

Forme

solid

Composition

loading of base, 14-16 wt. %

Pertinence de la réaction

core: lithium

Chaîne SMILES 

[Li+].[OH-]

InChI

1S/Li.H2O/h;1H2/q+1;/p-1

Clé InChI

WMFOQBRAJBCJND-UHFFFAOYSA-M

Description générale

Lithium hydroxide (LiOH) on glass beads. Lithium chloride solution in water on electrolysis forms LiOH. In respiratory apparatus and submarines, it is utilized to uptake carbon dioxide. A study on the redox mechanism of titanium dioxide (TiO2) using cyclic voltammetry, X-ray diffraction, X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR) in aqueous LiOH electrolyte has been reported.

Application

Lithium hydroxide has been used in the following processes: Synthesis of lithium-doped zinc oxide (ZnO) thin films. Preparation of lithium glyceroxide/hydroxide catalysts by reacting with glycerol. As a catalyst to generate unsaturated ketones via Michael addition of β-dicarbonyl compounds.

For general uses, product is also available in powdered form (545856)

Caractéristiques et avantages

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

Produit(s) apparenté(s)

Réf. du produit
Description
Tarif

Pictogrammes

Corrosion

Mention d'avertissement

Danger

Mentions de danger

Classification des risques

Eye Dam. 1 - Skin Corr. 1B

Code de la classe de stockage

8B - Non-combustible corrosive hazardous materials

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable


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Consulter la Bibliothèque de documents

Manuel Sturzbecher-Höhne et al.
Chemical research in toxicology, 21(12), 2257-2259 (2009-06-24)
We describe the preparation of aqueous solutions of LiONOO and NaONOO from (Me4N)ONOO. An aqueous solution of analytically pure, commercially available (Me4N)ONOO is applied to an Amberlyst 15 column at 4 degrees C, and the Me4N+ is rapidly (in 20
Cheng Guo et al.
Journal of the American Society for Mass Spectrometry, 23(7), 1191-1201 (2012-05-03)
Collision-induced dissociation (CID) of Li(+) adducts of three sets of compounds that contains an amide bond, including 2-(4, 6-dimethoxypyrimidin-2-ylsulfanyl)-N-phenylbenzamide, its derivatives and simpler structures was investigated by electrospray ionization tandem mass spectrometry (ESI-MS/MS). Observed fragment ions include those that reflect
Ana L Aguirre et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 27(51), 12981-12986 (2021-07-08)
High-throughput experimentation (HTE) methods are central to modern medicinal chemistry. While many HTE approaches to C-N and Csp2 -Csp2 bonds are available, options for Csp2 -Csp3 bonds are limited. We report here how the adaptation of nickel-catalyzed cross-electrophile coupling of
Noah P Tu et al.
Angewandte Chemie (International ed. in English), 58(24), 7987-7991 (2019-03-21)
Technologies that enable rapid screening of diverse reaction conditions are of critical importance to methodology development and reaction optimization, especially when molecules of high complexity and scarcity are involved. The lack of a general solid dispensing method for chemical reagents
Anja Kovanda et al.
Scientific reports, 5, 17944-17944 (2015-12-04)
The G4C2 hexanucleotide repeat expansion mutation (HREM) in C9ORF72, represents the most common mutation associated with amyotrophic lateral sclerosis (ALS) and frontotemporal lobar degeneration (FTLD). Three main disease mechanisms have been proposed to date: C9ORF72 haploinsufficiency, RNA toxicity, and accumulation

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