676578
Bis(tri-tert-butylphosphine)palladium(0)
Synonyme(s) :
Pd(t-Bu3P)2
About This Item
Produits recommandés
Forme
solid
Pertinence de la réaction
core: palladium
reagent type: catalyst
Capacité de réaction
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
Caractéristiques du produit alternatif plus écologique
Catalysis
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Pf
258-272 °C
Autre catégorie plus écologique
, Aligned
Température de stockage
−20°C
Chaîne SMILES
[Pd].CC(C)(C)P(C(C)(C)C)C(C)(C)C.CC(C)(C)P(C(C)(C)C)C(C)(C)C
InChI
1S/2C12H27P.Pd/c2*1-10(2,3)13(11(4,5)6)12(7,8)9;/h2*1-9H3;
Clé InChI
MXQOYLRVSVOCQT-UHFFFAOYSA-N
Description générale
Application
- Catalyst for Suzuki coupling on a multisubstituted sp3-carbon (eq. 1)
- Catalyst for Stille coupling reaction of aryl chlorides (eq. 2)
- Catalyst for Negishi coupling reaction (eq. 3)
- Catalyst for Heck coupling to form tetrasubstituted olefins (eq. 4)
- Catalyst for Buchwald-Hartwig amination of aryl halide (eq. 5)
- Catalyst for carbonylation of aryl halides with carbamoylsilanes (eq. 6)
On the Way Towards Greener Transition-Metal-Catalyzed Processes as Quantified by E Factors
Code de la classe de stockage
11 - Combustible Solids
Classe de danger pour l'eau (WGK)
WGK 3
Point d'éclair (°F)
Not applicable
Point d'éclair (°C)
Not applicable
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Articles
A variety of palladium-catalyzed cross-coupling reactions can be run under room temperature conditions in water with TPGS- 750-M, using a variety of commercially available palladium complexes and ligands.
A variety of palladium-catalyzed cross-coupling reactions can be run under room temperature conditions in water with TPGS- 750-M, using a variety of commercially available palladium complexes and ligands.
A variety of palladium-catalyzed cross-coupling reactions can be run under room temperature conditions in water with TPGS- 750-M, using a variety of commercially available palladium complexes and ligands.
A variety of palladium-catalyzed cross-coupling reactions can be run under room temperature conditions in water with TPGS- 750-M, using a variety of commercially available palladium complexes and ligands.
Protocoles
TPGS-750-M surfactant enables various reactions in water at room temperature, enhancing efficiency and versatility in synthesis.
TPGS-750-M surfactant enables various reactions in water at room temperature, enhancing efficiency and versatility in synthesis.
TPGS-750-M surfactant enables various reactions in water at room temperature, enhancing efficiency and versatility in synthesis.
TPGS-750-M surfactant enables various reactions in water at room temperature, enhancing efficiency and versatility in synthesis.
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