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348678

Sigma-Aldrich

Palladium

foil, thickness 1.0 mm, 99.9% trace metals basis

Synonym(s):

Palladium (powder), Palladium black, Palladium element

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About This Item

Linear Formula:
Pd
CAS Number:
Molecular Weight:
106.42
EC Number:
MDL number:
UNSPSC Code:
12141733
PubChem Substance ID:
NACRES:
NA.23

Assay

99.9% trace metals basis

form

foil

resistivity

9.96 μΩ-cm, 20°C

thickness

1.0 mm

bp

2970 °C (lit.)

mp

1554 °C (lit.)

density

12.02 g/cm3 (lit.)

SMILES string

[Pd]

InChI

1S/Pd

InChI key

KDLHZDBZIXYQEI-UHFFFAOYSA-N

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General description

Palladium and its alloys are used for hydrogen purification in fuel cells. Energy dispersive x-ray diffraction during electrochemical loading of palladium foils with hydrogen and deuterium was studied. Palladium foil was tested as a catalyst for Suzuki-Miyaura cross coupling reaction.

Quantity

7.6 g = 25 × 25 mm; 30.4 g = 50 × 50 mm

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Studies on the catalytic ability of palladium wire, foil and sponge in the Suzuki-Miyaura cross coupling
Amoroso F, et al.
Inorgorganica Chimica Acta, 375, 256-262 (2011)
In situ synchrotron energy-dispersive x-ray diffraction study of thin Pd foils with Pd:D and Pd:H concentrations up to 1:1
Knies DL, et al.
Journal of Applied Physics, 112 (2012)
Ling Li et al.
Nature chemistry, 5(7), 607-612 (2013-06-22)
The development of transition metal-catalysed cross-coupling reactions has greatly influenced the manner in which the synthesis of complex organic molecules is approached. A wide variety of methods are now available for the formation of C(sp(2))-C(sp(2)) bonds, and more recent work
Stefano Nicolai et al.
The Journal of organic chemistry, 78(8), 3783-3801 (2013-03-21)
Tetrahydrofurans and pyrrolidines are among the most important heterocycles found in bioactive compounds. Cyclization-functionalization domino reactions of alcohols or amines onto olefins constitute one of the most efficient methods to access them. In this context, oxy- and aminoalkynylation are especially
Xuxing Chen et al.
Organic & biomolecular chemistry, 11(16), 2582-2585 (2013-03-19)
A one-pot two-step synthesis of versatile indenones has been developed. This palladium(II)-catalyzed transformation involves generation and condensation of ortho-functionalized 1,2-benzils from 2-(2-arylethynylphenyl)acetonitriles using Ph2SO as the oxidant. The resulting 3-cyanoindenones can be converted to various valuable molecules.

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