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652407

Sigma-Aldrich

Tris(2,2′-bipyridyl-d8)ruthenium(II) hexafluorophosphate

95%

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About This Item

Empirical Formula (Hill Notation):
C30D24F12N6P2Ru
CAS Number:
Molecular Weight:
883.70
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:

Assay

95%

reaction suitability

reagent type: catalyst
core: ruthenium

mp

>300 °C (lit.)

mass shift

M+24

SMILES string

[Ru].F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.[2H]c1nc(c([2H])c([2H])c1[2H])-c2nc([2H])c([2H])c([2H])c2[2H].[2H]c3nc(c([2H])c([2H])c3[2H])-c4nc([2H])c([2H])c([2H])c4[2H].[2H]c5nc(c([2H])c([2H])c5[2H])-c6nc([2H])c([2H])c([2H])c6[2H]

InChI

1S/3C10H8N2.2F6P.Ru/c3*1-3-7-11-9(5-1)10-6-2-4-8-12-10;2*1-7(2,3,4,5)6;/h3*1-8H;;;/q;;;2*-1;+2/i3*1D,2D,3D,4D,5D,6D,7D,8D;;;

InChI key

KLDYQWXVZLHTKT-LUXBKWEBSA-N

General description

Fluorescent dye tris(2,2′-bipyridine)ruthenium has a high quenching coefficient k = 2.6%/oK.

Application

The emitting layers can be used as dopants for host materials in organic light emitting diodes and metal organic frameworks used for sensing, storage and catalysis applications.
High efficiency triplet emitter for OLED/Sensor research.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Photophysical Characterization of a Ruthenium(II) Tris(2,2?-bipyridine)-Doped Zirconium UiO-67 Metal?Organic Framework.
Maza WA and Morris AJ
The Journal of Physical Chemistry C null
Holographically patterned activation using photo-absorber induced neural?thermal stimulation
Farah N, et al.
Journal of Neural Engineering, 056004 null
Photophysical Characterization of a Ruthenium(II) Tris(2,2?-bipyridine)-Doped Zirconium UiO-67 Metal?Organic Framework.
Maza WA and Morris AJ
The Journal of Physical Chemistry C, 8803-8817 null
Holographically patterned activation using photo-absorber induced neural?thermal stimulation
Farah N, et al.
Journal of Neural Engineering null
Hongki Kang et al.
ACS nano, 14(9), 11406-11419 (2020-09-05)
Thermoplasmonic effect-based neural stimulation has been suggested as an alternative optical neural stimulation technology without genetic modification. Integration of near-infrared light with plasmonic gold nanoparticles has been demonstrated as a neuromodulation tool on in vitro neuronal network models. In order

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