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Clothianidin-d3

PESTANAL®, analytical standard

Synonym(s):

(E)-1-(2-Chloro-5-thiazolylmethyl)-3-(methyl-d3)-2-nitroguanidine

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About This Item

Empirical Formula (Hill Notation):
C6D3H5ClN5O2S
CAS Number:
1262776-24-8
Molecular Weight:
252.70
MDL number:
MFCD17019117
UNSPSC Code:
41116107
PubChem Substance ID:
329758241
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

Assay

≥97.0% (HPLC)

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

mass shift

M+3

SMILES string

[2H]C([2H])([2H])N\C(NCc1cnc(Cl)s1)=N/[N+]([O-])=O

InChI

1S/C6H8ClN5O2S/c1-8-6(11-12(13)14)10-3-4-2-9-5(7)15-4/h2H,3H2,1H3,(H2,8,10,11)/i1D3

InChI key

PGOOBECODWQEAB-FIBGUPNXSA-N

Related Categories

General description

Find more information here: Neonicotinoids

Application

Clothianidin-d3 may be used as a standard for the determination of neonicotinoid in milk by ultrahigh performance liquid chromatography coupled with tandem mass spectrometry (UHPLC-MS/MS).
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Exclamation markEnvironment
GHS07,GHS09

Signal Word

Warning

Hazard Statements

H302,H410

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
BCCM0953
BCCJ5146
BCCG1588
BCCD7505
BCBQ6968V

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Timothy A Bargar et al.
PeerJ, 8, e8669-e8669 (2020-03-21)
Recent concern for the adverse effects from neonicotinoid insecticides has centered on risk for insect pollinators in general and bees specifically. However, natural resource managers are also concerned about the risk of neonicotinoids to conservation efforts for the monarch butterfly
Development and Validation of an Ultra-Sensitive UHPLC-MS/MS Method for Neonicotinoid Analysis in Milk.
Lachat L and Glauser G
Journal of Agricultural and Food Chemistry, 66(32), 8639-8646 (2018)
Daniel B Pickford et al.
Environmental toxicology and chemistry, 37(4), 1040-1050 (2017-11-07)
Thiamethoxam is a widely used neonicotinoid insecticide that has been detected in surface water monitoring programs in North America and Europe. This has led to questions about its toxicity to nontarget insects, specifically those with an aquatic life stage. To
Lucas M Morrison et al.
Journal of AOAC International, 101(6), 1940-1947 (2018-05-23)
Background: Neonicotinoids are among the most widely used insecticides. Recently, there has been concern associated with unintended adverse effects on honeybees and aquatic invertebrates at low parts-per-trillion levels. Objective: There is a need for LC-MS/MS methods that are capable of
Junjie Zhang et al.
Talanta, 170, 392-398 (2017-05-16)
Extensive use of neonicotinoid insecticides has raised great concerns about their ecological risk. A reliable method to measure trace neonicotinoids in complicated aquatic environment is a premise for assessing their aquatic risk. To effectively remove matrix interfering substances from field
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