539759

8-Benzyloxyisosorbide triphenylphosphoylide solution

0.05 M in THF

• Synonym(s): Carb[(1R,4S,5R,8R)-8-benzyloxy-2,6-dioxabicyclo[3.3.0]octan-4-atemethylene]triphenylphosphorane
• Empirical Formula (Hill Notation): C₃₃H₃₁O₅P
• Molecular Weight: 538.57
• UNSPSC Code: 12352005
• PubChem Substance ID: 24878419

Properties

• optical activity: [α]20/D +1.7°, neat
• concentration: 0.05 M in THF
• refractive index: n20/D 1.413
• bp: 70-71 °C
• density: 0.882 g/mL at 25 °C
• storage temp.: 2-8°C
• SMILES string: O=C(O[C@H]1CO[C@@H]2[C@@H](CO[C@H]12)OCc3ccccc3)C=P(c4ccccc4)(c5ccccc5)c6ccccc6
• InChI: 1S/C33H31O5P/c34-31(38-30-23-37-32-29(22-36-33(30)32)35-21-25-13-5-1-6-14-25)24-39(26-15-7-2-8-16-26,27-17-9-3-10-18-27)28-19-11-4-12-20-28/h1-20,24,29-30,32-33H,21-23H2/t29-,30+,32-,33-/m1/s1
• InChI key: RFSVJVARGBBXNB-NKKCXFSRSA-N

Safety Information

• Pictograms: GHS02,GHS08,GHS07
• Signal Word: Danger
• Hazard Statements: H225,H302,H319,H335,H351
• Precautionary Statements: P210 - P280 - P301 + P312 + P330 - P305 + P351 + P338 - P370 + P378 - P403 + P235
• Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
• Target Organs: Respiratory system
• Supplementary Hazards: EUH019
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 2
• Flash Point(F): 1.4 °F
• Flash Point(C): -17.0 °C