- Dichlorido(furfuryl-amine-κN)(η-hexa-methyl-benzene)-ruthenium(II).
Dichlorido(furfuryl-amine-κN)(η-hexa-methyl-benzene)-ruthenium(II).
Acta crystallographica. Section E, Structure reports online (2012-01-06)
Amine Garci, Trieu-Tien Thai, Georg Süss-Fink, Bruno Therrien
PMID22219823
ZUSAMMENFASSUNG
The single-crystal X-ray structure analysis of [RuCl(2)(C(12)H(18))(C(5)H(7)NO)] reveals a distorted piano-stool geometry around the Ru(II) atom, with a hexa-methyl-benzene ligand, two chloride ligands and a furfuryl-amine ligand, the latter coordinating through the amine group. In the crystal, a dimeric structure is observed as a result of N-H⋯Cl inter-actions between two symmetry-related mol-ecules.
MATERIALIEN