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The synthesis of 2-deoxy-α-D-glycosides from D-glycals catalyzed by TMSI and PPh3.

Carbohydrate research (2012-08-03)
Xi-Kai Cui, Ming Zhong, Xiang-Bao Meng, Zhong-Jun Li
ZUSAMMENFASSUNG

2-Deoxyglycosides were synthesized in high α-selectivity by the direct addition of alcohols to D-glucal and D-galactal catalyzed by TMSI and PPh(3). The acid labile isopropylidene group is tolerated under this condition.

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Produktbeschreibung

Sigma-Aldrich
D-Glucal, 96%