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Merck

88559

Sigma-Aldrich

2,2′-Thiodiethanol

≥99.0% (GC)

Synonym(e):

2,2′-Thiobis-(ethanol), Bis-(2-hydroxyethyl)-sulfid, Thiodiethylenglycol, Thiodiglycol

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About This Item

Lineare Formel:
S(CH2CH2OH)2
CAS-Nummer:
Molekulargewicht:
122.19
Beilstein:
1236325
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352200
PubChem Substanz-ID:

Assay

≥99.0% (GC)

Brechungsindex

n20/D 1.521
n20/D 1.5215 (lit.)

bp

164-166 °C/20 mmHg (lit.)

mp (Schmelzpunkt)

−16 °C (lit.)

Dichte

1.221 g/mL at 25 °C (lit.)

SMILES String

OCCSCCO

InChI

1S/C4H10O2S/c5-1-3-7-4-2-6/h5-6H,1-4H2

InChIKey

YODZTKMDCQEPHD-UHFFFAOYSA-N

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Anwendung

Thiodiglycol (2,2′-Thiodiethanol, TDE) is used as a solvent and as a refractive index modifying component of mounting media for microscopy. Thiodiglycol may also be used as a charge modifier for procedures such as electrospray ionization mass spectrometry. Thiodiglycol is used as a reference material in the evaluation of the degradation of sulfur mustard gas by bacteria.

Sonstige Hinweise

This product has been replaced by 166782-ALDRICH | 2,2′-Thiodiethanol ≥99%

Piktogramme

Exclamation mark

Signalwort

Warning

H-Sätze

Gefahreneinstufungen

Eye Irrit. 2

Lagerklassenschlüssel

10 - Combustible liquids

WGK

WGK 1

Flammpunkt (°F)

235.4 °F - closed cup

Flammpunkt (°C)

113 °C - closed cup

Persönliche Schutzausrüstung

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


Analysenzertifikate (COA)

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S MOORE et al.
The Journal of biological chemistry, 192(2), 663-681 (1951-10-01)
Julien Besnard et al.
Journal of experimental botany, 69(21), 5221-5232 (2018-10-13)
Phloem-derived amino acids are the major source of nitrogen supplied to developing seeds. Amino acid transfer from the maternal to the filial tissue requires at least one cellular export step from the maternal tissue prior to the import into the
N Medvedeva et al.
Environmental research, 106(3), 289-295 (2007-06-01)
A special group of substances that are very dangerous for the biosphere includes war gases such as mustard gas (bis(2-chloroethyl)sulphide). The influence of mustard gas hydrolysis products (MGHPs) on soil microbiota has been investigated. These substances bear numerous toxic effects
Anne E Boyer et al.
Journal of analytical toxicology, 28(5), 327-332 (2004-07-09)
Sulfur mustard (HD), or bis(2-chloroethyl)sulfide, has several urinary metabolites that can be measured to assess human exposure. These metabolites include the simple hydrolysis product thiodiglycol (TDG) and its oxidative analogue, TDG-sulfoxide, as well as metabolites of the glutathione/b-lyase pathway 1,1'-sulfonylbis[2-(methyl-sulfinyl)ethane]
Isaac Ohsawa et al.
Journal of chromatography. A, 1061(2), 235-241 (2005-01-12)
A method for determining thiodiglycol (TDG), a mustard gas hydrolysis product in water, serum and urine samples using gas chromatography-mass spectrometry (GC-MS) after tert-butyldimethylsilylation (TBDMS) is described. Quantitation of TDG was performed by measuring the respective peak area on the

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