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Merck

36197

Supelco

Phoxim

PESTANAL®, analytical standard

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About This Item

Empirische Formel (Hill-System):
C12H15N2O3PS
CAS-Nummer:
Molekulargewicht:
298.30
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
41116107
PubChem Substanz-ID:
NACRES:
NA.24

Qualität

analytical standard

Qualitätsniveau

Produktlinie

PESTANAL®

Haltbarkeit

limited shelf life, expiry date on the label

Methode(n)

HPLC: suitable
gas chromatography (GC): suitable

Anwendung(en)

agriculture
environmental

Format

neat

Lagertemp.

2-8°C

SMILES String

CCOP(=S)(OCC)O\N=C(/C#N)c1ccccc1

InChI

1S/C12H15N2O3PS/c1-3-15-18(19,16-4-2)17-14-12(10-13)11-8-6-5-7-9-11/h5-9H,3-4H2,1-2H3/b14-12+

InChIKey

ATROHALUCMTWTB-WYMLVPIESA-N

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Allgemeine Beschreibung

Phoxims are classified under the organophosphorus group of pesticides.

Anwendung

Phoxim may be used as an analytical reference standard for the determination of phoxim in:
  • Honeys, honeybees and pollens and food samples by QuEChERS extraction followed by analysis using liquid chromatography-electrospray ionization-tandem mass spectrometry (LC-ESI-LC-MS/MS) combined with multiple reaction monitoring (MRM) detection.
  • Egg samples by acetonitrile-based extraction and high performance liquid chromatography-diode array detection (HPLC-DAD).
  • Environmental samples by temperature-controlled ionic liquid dispersive liquid-phase extraction and HPLC combined with ultraviolet (UV) detection.

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Sonstige Hinweise

blocked due to transport restrictions

Rechtliche Hinweise

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Repr. 2 - Skin Sens. 1

Lagerklassenschlüssel

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Analysenzertifikate (COA)

Lot/Batch Number

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Rui Zhang et al.
Molecules (Basel, Switzerland), 24(6) (2019-03-17)
A method for detecting the organophosphorus pesticides residue and aflatoxins in China herbal tea has been developed by UPLC-MS/MS coupled with vortex-assisted dispersive liquid-liquid microextraction (DLLME). The extraction conditions for vortex-assisted DLLME extraction were optimized using single-factor experiments and response
Borris Meyer-Kühling et al.
Veterinary parasitology, 147(3-4), 289-296 (2007-06-05)
Infestations with the poultry red mite Dermanyssus gallinae represent a major ectoparasite problem in poultry and can affect egg layers worldwide. There is presently a lack of an ectoparasiticide in Europe for poultry which can assure a 0-day withholding period
Ke Dai et al.
Environmental science & technology, 43(5), 1540-1545 (2009-04-09)
Photocatalytic degradation of commercial phoxim emulsion in aqueous suspension was investigated by using La-doped mesoporous TiO2 nanoparticles (m-TiO2) as the photocatalyst under UV irradiation. Effects of La-doping level, calcination temperature, and additional amount of the photocatalyst on the photocatalytic degradation
Bing Li et al.
Chemosphere, 89(5), 609-614 (2012-06-12)
Phoxim insecticide is widely used in agriculture, which is toxic to insect pests and nontarget organisms. The phoxim poisoning is hard to prevent for silkworms. TiO(2) NPs have been widely applied in whitening, brightening foods, toothpaste or sunscreens, and orally-administered
Yi Hui Zhang et al.
Archives of toxicology, 81(11), 785-792 (2007-05-31)
The hydrolysis of acetylthiocholine iodide (ATCh) by pralidoxime chloride (2-PAM Cl), trimedoxime (TMB(4)) and obidoxime chlpride (LUH(6)) was studied at pH 5.8-8.0 and incubation temperature from 5 to 40 degrees C in vitro. Significant ATCh hydrolysis by 2-PAM Cl, TMB(4)

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