708275

1,3-Bis-(2,6-diisopropylphenyl)-[1,3,2]diazaphospholidin-2-oxid

97%

• Synonym(e): 1,3-Bis[2,6-bis(1-methylethyl)phenyl]-1,3,2-diazaphospholidine 2-oxide
• Empirische Formel (Hill-System): C₂₆H₃₉N₂OP
• CAS-Nummer: 854929-36-5
• Molekulargewicht: 426.57
• MDL-Nummer: MFCD14708169
• UNSPSC-Code: 12352005
• PubChem Substanz-ID: 329762783

Eigenschaften

• Assay: 97%
• Form: solid
• Eignung der Reaktion: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand
• mp (Schmelzpunkt): 205-210 °C
• Funktionelle Gruppe: phosphine
• SMILES String: CC(C)c1cccc(C(C)C)c1N2CCN(c3c(cccc3C(C)C)C(C)C)[PH]2=O
• InChI: 1S/C26H39N2OP/c1-17(2)21-11-9-12-22(18(3)4)25(21)27-15-16-28(30(27)29)26-23(19(5)6)13-10-14-24(26)20(7)8/h9-14,17-20,30H,15-16H2,1-8H3
• InChIKey: SQYNIVDXVZPMLW-UHFFFAOYSA-N

Beschreibung

Anwendung

Reactnat for synthesis of air-stable palladium HASPO complexes

Catalyst for:

• Dehydrative direct arylations of arenes
• Aryl-(hetero)aryl coupling by activation of C-Cl and C-F bonds

Ligand used with ruthenium for dehydrative direct arylation of arenes with phenols

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 2
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type N95 (US)