543144

6-Chlor-1-hexen

96%

• Lineare Formel: Cl(CH₂)₄CH=CH₂
• CAS-Nummer: 928-89-2
• Molekulargewicht: 118.60
• EG-Nummer: 213-186-5
• MDL-Nummer: MFCD00039391
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24878665
• NACRES: NA.22

Eigenschaften

• Assay: 96%
• Brechungsindex: n20/D 1.438 (lit.)
• bp: 135-136 °C (lit.)
• Dichte: 0.896 g/mL at 25 °C (lit.)
• SMILES String: ClCCCCC=C
• InChI: 1S/C6H11Cl/c1-2-3-4-5-6-7/h2H,1,3-6H2
• InChIKey: BLMIXWDJHNJWDT-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

6-Chloro-1-hexene is an ω-chloro-1-alkene. It reacts with β-substituted imines in the presence of a rhodium catalyst to afford tri- and tetra-substituted imines. It undergoes cross-coupling reaction in the presence of copper(II) chloride and 1-phenylpropyne.

Anwendung

6-Chloro-1-hexene may be used in the synthesis of 1-(5-hexen)-2,3-dimethyl-imidazolium chloride.

Sicherheitshinweise

• Piktogramme: GHS02,GHS07
• Signalwort: Warning
• H-Sätze: H226,H315,H319,H335
• P-Sätze: P210 - P233 - P240 - P241 - P303 + P361 + P353 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 3
• Flammpunkt (°F): 84.0 °F - closed cup
• Flammpunkt (°C): 28.9 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter