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Dokumente

343536

Sigma-Aldrich

1-Boc-piperazin

97%

Synonym(e):

Piperazin-1-carbonsäure-tert.-butylester

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About This Item

Empirische Formel (Hill-System):
C9H18N2O2
CAS-Nummer:
57260-71-6
Molekulargewicht:
186.25
Beilstein:
879985
MDL-Nummer:
MFCD00075265
UNSPSC-Code:
12352100
PubChem Substanz-ID:
24861171
NACRES:
NA.22

Assay

97%

Form

solid

mp (Schmelzpunkt)

43-47 °C (lit.)

SMILES String

CC(C)(C)OC(=O)N1CCNCC1

InChI

1S/C9H18N2O2/c1-9(2,3)13-8(12)11-6-4-10-5-7-11/h10H,4-7H2,1-3H3

InChIKey

CWXPZXBSDSIRCS-UHFFFAOYSA-N

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Allgemeine Beschreibung

Prepared in 80% yield via solvent-free N-Boc protection catalyzed by iodine.

Anwendung

Preparation of monosubstituted piperazines, e.g. in the synthesis of indazole DNA gyrase inhibitors.

Piktogramme

Exclamation mark
GHS07

Signalwort

Warning

Gefahreneinstufungen

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Zielorgane

Respiratory system

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 3

Flammpunkt (°F)

235.4 °F - closed cup

Flammpunkt (°C)

113 °C - closed cup

Persönliche Schutzausrüstung

dust mask type N95 (US), Eyeshields, Gloves

Analysenzertifikate (COA)

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1-Boc-4-(3-Hydroxypropyl)piperazin 97%

Sigma-Aldrich

643467

1-Boc-4-(3-Hydroxypropyl)piperazin

1-Methylpiperazin 99%

Sigma-Aldrich

130001

1-Methylpiperazin

Dengfeng Dou et al.
Bioorganic & medicinal chemistry letters, 22(1), 377-379 (2011-11-29)
There is currently an unmet need for the development of small-molecule therapeutics for norovirus infection. The piperazine scaffold, a privileged structure embodied in many pharmacological agents, was used to synthesize an array of structurally-diverse derivatives which were screened for anti-norovius
Akihiko Tanitame et al.
Bioorganic & medicinal chemistry letters, 14(11), 2857-2862 (2004-05-06)
In this study, we report the design, synthesis and structure-activity relationships of novel indazole derivatives as DNA gyrase inhibitors with Gram-positive antibacterial activity. Our results show that selected compounds from this series exhibit potent antibacterial activity against Gram-positive bacteria including
Florencio Zaragoza et al.
Journal of medicinal chemistry, 47(11), 2833-2838 (2004-05-14)
With the aim of identifying structurally novel, centrally acting histamine H(3) antagonists, arrays of monoacyldiamines were screened. This led to the discovery of a series of 1-alkyl-4-acylpiperazines which were potent antagonists at the human histamine H(3) receptor. The most potent
Ravi Varala et al.
The Journal of organic chemistry, 71(21), 8283-8286 (2006-10-10)
An efficient and practical protocol for the protection of various structurally and electronically divergent aryl and aliphatic amines using (Boc)2O in the presence of a catalytic amount of molecular iodine (10 mol %) under solvent-free conditions at ambient temperature is
α,ω-Functionalized Poly (2-Oxazoline) s Bearing Hydroxyl and Amino Functions.
Reif M and Jordan R.
Macromolecular Chemistry and Physics, 212(16), 1815-1824 (2011)
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