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Key Documents

34850-M

Sigma-Aldrich

Acetone

suitable for HPLC, ≥99.8%

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About This Item

Lineární vzorec:
CH3COCH3
Číslo CAS:
Molekulová hmotnost:
58.08
Beilstein/REAXYS Number:
635680
EC Number:
MDL number:
UNSPSC Code:
12190000
eCl@ss:
39021201
PubChem Substance ID:
NACRES:
NA.02

grade

HPLC grade

vapor density

2 (vs air)

vapor pressure

184 mmHg ( 20 °C)

assay

≥99.8%

form

liquid

autoignition temp.

465 °C (869 °F)

expl. lim.

13.2 %

technique(s)

HPLC: suitable

impurities

≤0.0005% non-volatile matter
≤0.002% free acid (as CH3COOH)
≤0.1% water (Karl Fischer)

transmittance

330 nm, ≥15%
335 nm, ≥50%
340 nm, ≥80%
350 nm, ≥98%

refractive index

n20/D 1.359 (lit.)

pH

(5 - 6 at 395 g/l at 20 °C (68 °F))

bp

56 °C/760 mmHg (lit.)

mp

−94 °C (lit.)

solubility

water: miscible

density

0.791 g/mL at 25 °C (lit.)

application(s)

general analytical

format

neat

SMILES string

CC(C)=O

InChI

1S/C3H6O/c1-3(2)4/h1-2H3

InChI key

CSCPPACGZOOCGX-UHFFFAOYSA-N

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General description

Mixtures of TiO2 (P25) with rare earth oxides (La2O3 or Y2O3) calcined at 700°C or 650°C efficiently causes oxidation of acetone. Its Aldol condensation in vapor-phase has been investigated over MgO promoted with alkali (Li, Na, K and Cs) or alkaline earth (Ca, Sr and Ba) metal ions. It undergoes Aldol condensation in the presence of Mg-Al layered double hydroxides (LDH) as catalysts and Cl- and/or CO32- as compensating anions to afford diacetone alcohol and mesityl oxide. Enantioselective Aldol condensation of acetone with various isatins in the presence of dipeptides (catalyst) has been described.

Application

Acetone has been used in the preparation of 13wt% amorphous poly (lactic acid) (PLA) solution, which was required for the preparation of electrospun PLA membranes.
Acetone′s luminesence intensity is dependent upon the solution components . The absorption of UV light by acetone, results in its photolysis and the production of radials .

Other Notes

Important notice
  • The article number 34850-4X2.5L-M will be discontinued. Please order the single bottle 34850-2.5L-M which is physically identical with the same exact specifications.
  • The article number 34850-6X1L-M will be discontinued. Please order the single bottle 34850-1L-M which is physically identical with the same exact specifications.

Recommended products

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pictograms

FlameExclamation mark

signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

target_organs

Central nervous system

supp_hazards

Storage Class

3 - Flammable liquids

wgk_germany

WGK 1

flash_point_f

1.4 °F - closed cup

flash_point_c

-17.00 °C - closed cup


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Gianluigi Luppi et al.
The Journal of organic chemistry, 70(18), 7418-7421 (2005-08-27)
[reaction: see text] The aldol condensation of acetone with several isatins is described. The desired compound was obtained in quantitative yield and with good enantioselectivities up to 77%. The best results were obtained with 10 mol % H-D-Pro-L-beta3-hPhg-OBn as a

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