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08603

Supelco

tert-Butyl methyl ether

analytical standard

Synonyma:

MTBE, Methyl tert-butyl ether

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About This Item

Lineární vzorec:
(CH3)3COCH3
Číslo CAS:
1634-04-4
Molekulová hmotnost:
88.15
Beilstein/REAXYS Number:
1730942
EC Number:
216-653-1
MDL number:
MFCD00008812
UNSPSC Code:
41116107
PubChem Substance ID:
329748620
NACRES:
NA.24

grade

analytical standard

Quality Level

100

vapor density

3.1 (vs air)

assay

≥99.9% (GC)

autoignition temp.

705 °F

shelf life

limited shelf life, expiry date on the label

expl. lim.

15.1 %

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

refractive index

n20/D 1.369 (lit.)
n20/D 1.369

bp

55-56 °C (lit.)

density

0.74 g/mL at 25 °C (lit.)

application(s)

environmental

format

neat

SMILES string

COC(C)(C)C

InChI

1S/C5H12O/c1-5(2,3)6-4/h1-4H3

InChI key

BZLVMXJERCGZMT-UHFFFAOYSA-N

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Související kategorie

General description

tert-Butyl methyl ether or methyl tert-butyl ether (MTBE) is an oxygenated compound.. It is commonly used as a gasoline additive in fuel. Though it is known to control air pollution, it is a potential groundwater pollutant.

Application

MTBE may be used as a reference standard for the determination of MTBE in water by headspace-solid-phase microextraction (headspace-SPME) method.

Recommended products

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Danger

hcodes

H225,H315

Hazard Classifications

Flam. Liq. 2 - Skin Irrit. 2

Storage Class

3 - Flammable liquids

wgk_germany

WGK 1

flash_point_f

-18.4 °F - closed cup

flash_point_c

-28 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves

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Osvědčení o analýze (COA)

Lot/Batch Number
BCCM0376
BCCK0523
BCCH1746
BCCD4770
BCCB8083

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tert-Butyl methyl ether for liquid chromatography LiChrosolv®

Supelco

1.01845

tert-Butyl methyl ether

tert-Amyl methyl ether analytical standard

Supelco

442794

tert-Amyl methyl ether

Acetonitrile analytical standard

Supelco

45983

Acetonitrile

tert-Butyl ethyl ether purum, ≥97.0% (GC)

Sigma-Aldrich

03202

tert-Butyl ethyl ether

Analysis of methyl tert-butyl ether (MTBE) and tert-butyl alcohol (TBA) in ground and surface water.
Schmidt TC.
TrAC, Trends in Analytical Chemistry, 22(10), 776-784 (2003)
Sensitive method for determination of methyl tert-butyl ether (MTBE) in water by use of headspace-SPME/GC-MS.
Achten C, et al.
Fresenius Journal of Analytical Chemistry, 371(4), 519-525 (2001)
The effects of methyl tert-butyl ether (MTBE) on the male rat reproductive system.
Li D, et al.
Food And Chemical Toxicology, 46(7), 2402-2408 (2008)
Tobias Langenberg et al.
Cell reports, 31(2), 107512-107512 (2020-04-16)
The amyloid-like aggregation propensity present in most globular proteins is generally considered to be a secondary side effect resulting from the requirements of protein stability. Here, we demonstrate, however, that mutations in the globular and amyloid state are thermodynamically correlated
Sarah K Abbott et al.
Lipids, 48(3), 307-318 (2013-01-29)
We have developed a protocol suitable for high-throughput lipidomic analysis of human brain samples. The traditional Folch extraction (using chloroform and glass-glass homogenization) was compared to a high-throughput method combining methyl-tert-butyl ether (MTBE) extraction with mechanical homogenization utilizing ceramic beads.
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