00790

Acetophenone

≥99.0% (GC), liquid, puriss. p.a.

• Synonyma: Methyl phenyl ketone
• Lineární vzorec: CH₃COC₆H₅
• Číslo CAS: 98-86-2
• Molekulová hmotnost: 120.15
• NACRES: NA.21
• PubChem Substance ID: 329747139
• eCl@ss: 39023804
• UNSPSC Code: 12352100
• EC Number: 202-708-7
• MDL number: MFCD00008724
• Beilstein/REAXYS Number: 605842
• Assay: ≥99.0% (GC)
• Form: liquid

Vlastnosti

• Název produktu: Acetophenone, puriss. p.a., ≥99.0% (GC)
• vapor density: 4.1 (vs air)
• Quality Segment: 200
• vapor pressure: 0.45 mmHg ( 25 °C), 1 mmHg ( 15 °C)
• grade: puriss. p.a.
• assay: ≥99.0% (GC)
• form: liquid
• autoignition temp.: 1058 °F
• impurities: ≤0.02% free acid (as CH₃COOH), ≤0.3% water
• refractive index: n20/D 1.534 (lit.), n20/D 1.535
• bp: 202 °C (lit.)
• mp: 19-20 °C (lit.)
• transition temp: solidification point 19-20 °C
• density: 1.03 g/mL at 25 °C (lit.)
• cation traces: Al: ≤0.5 mg/kg, Ba: ≤0.1 mg/kg, Bi: ≤0.1 mg/kg, Ca: ≤0.5 mg/kg, Cd: ≤0.05 mg/kg, Co: ≤0.02 mg/kg, Cr: ≤0.02 mg/kg, Cu: ≤0.02 mg/kg, Fe: ≤0.1 mg/kg, K: ≤0.5 mg/kg, Li: ≤0.1 mg/kg, Mg: ≤0.1 mg/kg, Mn: ≤0.02 mg/kg, Mo: ≤0.1 mg/kg, Na: ≤0.5 mg/kg, Ni: ≤0.02 mg/kg, Pb: ≤0.1 mg/kg, Sr: ≤0.1 mg/kg, Zn: ≤0.1 mg/kg
• functional group: ketone, phenyl
• SMILES string: CC(=O)c1ccccc1
• InChI: 1S/C8H8O/c1-7(9)8-5-3-2-4-6-8/h2-6H,1H3
• InChI key: KWOLFJPFCHCOCG-UHFFFAOYSA-N

Popis

General description

Acetophenone (Methyl phenyl ketone) is an alkyl phenyl ketone. Its triplet absorption spectra in non-polar solvents has been evaluated by nanosecond laser photolysis. Photoreduction of acetophenone has been investigated. N-chelate ligands based on chiral oxazolines catalyzed enantioselective hydrosilylation of acetophenone with α-naphtylphenylsilane has been reported. Intersystem crossing of aromatic aldehydes and ketones (benzaldehyde, acetophenone and benzophenone) has been studied. Rhodium(I) complexes containing optically active 2-(2′-pyridyl)pyridines efficiently catalyzes the reduction of acetophenone.

Bezpečnostní informace

• pictograms: GHS07
• signalword: Warning
• hcodes: H302,H319
• pcodes: P264 - P280 - P301 + P312 - P305 + P351 + P338 - P337 + P313 - P501
• Hazard Classifications: Acute Tox. 4 Oral - Eye Irrit. 2
• Skladovací třída: 10 - Combustible liquids
• wgk: WGK 1
• flash_point_f: 179.6 °F - closed cup
• flash_point_c: 82 °C - closed cup
• ppe: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter