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Sigma-Aldrich

Grubbs Catalyst® M300

Synonyma:

Grubbs Catalyst® 3rd Generation, Grubbs Catalyst® M37a (C884), Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene](benzylidene)bis(3-bromopyridine)ruthenium(II), Grubbs Catalyst® C884, [1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(phenylmethylene)bis(3-bromopyridine)ruthenium(II), [1,3-Dimesityl-2-imidazolidinylidene]dichloro(phenylmethylene)bis(3-bromopyridine)ruthenium(II)

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About This Item

Empirický vzorec (Hillův zápis):
C38H40Br2Cl2N4Ru
Číslo CAS:
900169-53-1
Molekulová hmotnost:
884.54
MDL number:
MFCD09265164
UNSPSC Code:
12161600
PubChem Substance ID:
329760489
NACRES:
NA.22

reaction suitability

core: ruthenium
reagent type: catalyst
reaction type: Ring-Opening Polymerization

mp

140 °C (dec.)

storage temp.

2-8°C

SMILES string

Brc1cccnc1.Brc2cccnc2.Cc3cc(C)c(N4CCN(C4=[Ru](Cl)(Cl)=Cc5ccccc5)c6c(C)cc(C)cc6C)c(C)c3

InChI

1S/C21H26N2.C7H6.2C5H4BrN.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-7-5-3-2-4-6-7;2*6-5-2-1-3-7-4-5;;;/h9-12H,7-8H2,1-6H3;1-6H;2*1-4H;2*1H;/q;;;;;;+2/p-2

InChI key

YDOACSUCKSODBO-UHFFFAOYSA-L

Související kategorie

Application

Metathesis: Ruthenium-Based Metathesis Catalysts
Labile pyridine ligands result in a very fast initiator (even at 0 °C). Effective in cross metathesis of acrylonitrile. Also effective in RCM and the ROMP production of block copolymers and polymers with narrow PDIs.

Other Notes

Grubbs Catalyst® Technology for Olefin Metathesis by Aldrich

Legal Information

Product License
This product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer′s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.

For any further information on product please refer to your local Umicore PMC contact at www.pmc.umicore.com.
Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Osvědčení o analýze (COA)

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Navštívit knihovnu dokumentů

Sanford, M. S., et al.
Organometallics, 5314-5314 (2001)
A practical and highly active ruthenium-based catalyst that effects the cross metathesis of acrylonitrile.
Jennifer A Love et al.
Angewandte Chemie (International ed. in English), 41(21), 4035-4037 (2002-11-02)
Ritter, T., et al.
Organometallics, 5740-5740 (2006)
Choi TL, and Grubbs RH.
Aldrichimica Acta, 42(15), 1743-1746 (2003)
Takuya Kanemitsu et al.
Organic letters, 5(24), 4541-4544 (2003-11-25)
[reaction: see text] The octenediol linker used during automated oligosaccharide assembly is cleaved by olefin cross-metathesis. Until now, this linker could not be applied to sugars containing azides. A detailed study of the cleavage reaction served as basis for the
Zobrazit všechny související dokumenty

Související obsah

Grubbs Group – Professor Product Portal

Research in the Grubbs group has centered on the development and application of a suite of highly active, selective, and bench stable ruthenium alkylidene complexes capable of catalyzing versatile olefin metatheses.

Náš tým vědeckých pracovníků má zkušenosti ve všech oblastech výzkumu, včetně přírodních věd, materiálových věd, chemické syntézy, chromatografie, analytiky a mnoha dalších..

Obraťte se na technický servis.