912409
High-performance silicon anode
1 micron silicon particles in crosslinked conducting polyanaline matrix
Synonym(s):
Doped polyaniline, Si encapsulated in 3D crosslinked polyaniline, Si/PANi composite, Silicon micron particle
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About This Item
UNSPSC Code:
12352103
NACRES:
NA.23
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Quality Level
form
solid
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Application
Silicon is a most promising next generation lithium ion battery electrode material, due to its ~10 times higher specific capacity (3600 mAh/g) than graphite (372 mAh/g). However, silicon experiences large volume change (~400%) during lithium insertion, causing it to fracture and detach from current collector, rendering prototypical lithium-silicon batteries to lose most of their capacity in less than 10 charge-discharge cycles. A solution to the capacity and stability issues posed by the significant volume expansion upon lithiation of silicon is critical to the success of high capacity lithium ion batteries.
This silicon/PANi composite utilizes a doped, intrinsically conductive, 3D cross-linked polyaniline as matrix, which could function as both the conductive binder and the polymer electrolyte for silicon-based electrodes. Previous study for a similar silicon-based three-dimensional conducting polymer composite demonstrated increased electrochemically performance due to short diffusion paths and good 3D connectivity, and resulted in a marked improvement in cyclability, with over 90% capacity retention after 5,000 cycles.
This composite is made by encapsulating silicon particles in an in-situ polymerized 3D-crosslinked conductive polyaniline framework. This Si/PANi composite not only allows fast electrical and ionic transport, but also provides free space to allow giant volume expansion. This Si/PANi composite provides a ready-to-use electrochemically active silicon composite that would increase the capacity of conventional lithium ion battery, and improve the cycle-life of Si-based anodes.
This silicon/PANi composite utilizes a doped, intrinsically conductive, 3D cross-linked polyaniline as matrix, which could function as both the conductive binder and the polymer electrolyte for silicon-based electrodes. Previous study for a similar silicon-based three-dimensional conducting polymer composite demonstrated increased electrochemically performance due to short diffusion paths and good 3D connectivity, and resulted in a marked improvement in cyclability, with over 90% capacity retention after 5,000 cycles.
This composite is made by encapsulating silicon particles in an in-situ polymerized 3D-crosslinked conductive polyaniline framework. This Si/PANi composite not only allows fast electrical and ionic transport, but also provides free space to allow giant volume expansion. This Si/PANi composite provides a ready-to-use electrochemically active silicon composite that would increase the capacity of conventional lithium ion battery, and improve the cycle-life of Si-based anodes.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Deformation and stress in electrode materials for Li-ion batteries.
Mukhopadhyay A, et al.
Progress in Materials Science, 63, 58-116 (2014)
Ye Shi et al.
Nano letters, 17(3), 1906-1914 (2017-02-14)
Controlling architecture of electrode composites is of particular importance to optimize both electronic and ionic conduction within the entire electrode and improve the dispersion of active particles, thus achieving the best energy delivery from a battery. Electrodes based on conventional
Borui Liu et al.
Nano letters, 13(7), 3414-3419 (2013-06-22)
Silicon is considered one of the most promising anode materials for high-performance Li-ion batteries due to its 4200 mAh/g theoretical specific capacity, relative abundance, low cost, and environmental benignity. However, silicon experiences a dramatic volume change (∼300%) during full charge/discharge
Ye Shi et al.
Advanced materials (Deerfield Beach, Fla.), 29(22) (2017-03-23)
This study develops a tunable 3D nanostructured conductive gel framework as both binder and conductive framework for lithium ion batteries. A 3D nanostructured gel framework with continuous electron pathways can provide hierarchical pores for ion transport and form uniform coatings
Hui Wu et al.
Nature communications, 4, 1943-1943 (2013-06-05)
Silicon has a high-specific capacity as an anode material for Li-ion batteries, and much research has been focused on overcoming the poor cycling stability issue associated with its large volume changes during charging and discharging processes, mostly through nanostructured material
Articles
Recent demand for electric and hybrid vehicles, coupled with a reduction in prices, has caused lithium-ion batteries (LIBs) to become an increasingly popular form of rechargeable battery technology.
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