134236

Morpholine

ReagentPlus^®, ≥99%

• Synonym(s): Tetrahydro-1,4-oxazine
• Empirical Formula (Hill Notation): C₄H₉NO
• CAS Number: 110-91-8
• Molecular Weight: 87.12
• Beilstein: 102549
• EC Number: 203-815-1
• MDL number: MFCD00005972
• UNSPSC Code: 12352100
• eCl@ss: 39162409
• PubChem Substance ID: 24848140
• NACRES: NA.21

Properties

• vapor density: 3 (vs air)
• Quality Level: 200
• vapor pressure: 31 mmHg ( 38 °C); 7 mmHg ( 20 °C)
• product line: ReagentPlus^®
• Assay: ≥99%
• form: liquid
• autoignition temp.: 590 °F
• expl. lim.: 10.8 %
• refractive index: n20/D 1.454 (lit.)
• bp: 129 °C (lit.)
• mp: −7-−5 °C (lit.)
• density: 0.996 g/mL at 25 °C (lit.)
• SMILES string: C1COCCN1
• InChI: 1S/C4H9NO/c1-3-6-4-2-5-1/h5H,1-4H2
• InChI key: YNAVUWVOSKDBBP-UHFFFAOYSA-N

Description

General description

Morpholine can be obtained, via degradation of N-methylmorpholine N-oxide (NMMO) during fiber production.

Morpholine is a cyclic amine that serves as a solvent, corrosion inhibitor, and chemical intermediate.

Application

Morpholine can be used as a buffer component in the separation of peptides and pathogenic lipopolysaccharides during on-line chromatographic preconcentration coupled to capillary zone electrophoresis–electrospray mass spectrometry (cPC–CZE–ES-MS) analysis from colony isolates.

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Safety Information

• Pictograms: GHS02,GHS06,GHS08,GHS05
• Signal Word: Danger
• Hazard Statements: H226,H302,H311 + H331,H314,H361fd
• Precautionary Statements: P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Repr. 2 - Skin Corr. 1B
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 1
• Flash Point(F): 87.8 °F - closed cup
• Flash Point(C): 31 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves