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919594

Sigma-Aldrich

Pd(IPr#)(AN)Cl2

≥95%

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About This Item

Empirical Formula (Hill Notation):
C99H79Cl2N3Pd
Molecular Weight:
1488.03
NACRES:
NA.22

Quality Level

Assay

≥95%

form

powder

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

mp

>300 °C

Application

Pd(IPr#)(AN)Cl2 is a Pd-catalyst that can be used in a broad range of reactions, including cross-coupling, C-H functionalization, electrophilic additions. NHC-Pd-aniline complexes of this type have many advantages, including higher reactivity in cross-coupling reactions than similar complexes using cinnamyl and pyridine throw-away ligands and simple reaction tunability through substituion of aniline ligand.

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Product No.
Description
Pricing

Storage Class Code

11 - Combustible Solids

WGK

WGK 3


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Qun Zhao et al.
Chemical science, 12(31), 10583-10589 (2021-08-28)
IPr (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) represents the most important NHC (NHC = N-heterocyclic carbene) ligand throughout the field of homogeneous catalysis. Herein, we report the synthesis, catalytic activity, and full structural and electronic characterization of novel, sterically-bulky, easily-accessible NHC ligands based

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