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US EPA Method 8015 (modified): GC Analysis of Gasoline Range Organics (GRO) on Equity-1 after Purge & Trap using "M" Trap

US EPA Method 8015 (modified): GC Analysis of Gasoline Range Organics (GRO) on Equity-1 after Purge & Trap using "M" Trap suitable for GC

Materiales

Analytical column

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Equity-1

L × I.D. 30 m × 0.32 mm, df 1.00 μm

SLB®-5ms Capillary GC Column

L × I.D. 30 m × 0.25 mm, df 0.25 μm

SLB®-5ms Capillary GC Column

L × I.D. 30 m × 0.25 mm, df 0.50 μm

SLB®-5ms Capillary GC Column

L × I.D. 20 m × 0.18 mm, df 0.18 μm

For use with

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Wheaton wide-mouth bottle

amber soda-lime glass bottle, capacity 1000 mL, white polypropylene cap, (PTFE faced LDPE liner), case of 12 ea

Férula de doble cono Supeltex M-2B

I.D. 0.4 mm, 0.10-0.25 mm to like I.D. Column, pkg of 2 ea

Capillary Column Butt Connector

body only (ferrules not included)

Guard column

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Intermediate Polarity Fused Silica Tubing

L × I.D. 5.0 m × 0.25 mm

standard

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N-Nitrosodiphenylamine solution

certified reference material, 5000 μg/mL in methanol

Perfluorotributylamine

analytical standard

EPA 8270 GC-MS Tuning Solution II

certified reference material, 1000 μg/mL each component in dichloromethane

CLP Semivolatile Calibration Mix

certified reference material, 1000 μg/mL each component in dichloromethane : benzene (3:1)

CLP Semivolatiles Surrogate Standards Mix

certified reference material, 4000 μg/mL each component in methylene chloride

Semivolatile Internal Standards Mix

certified reference material, TraceCERT®, 2000 μg/mL each component in methylene chloride, ampule of 2 × 1 mL

EPA 8270 Benzidines Mix

certified reference material, TraceCERT®, 2000 μg/mL each component in methanol, ampule of 1 mL

CONDITIONS

sample/matrix

Each analyte at 50 ppb in 5 mL of water

purge trap

MOD BTEXTRAP M, Tekmar® 3000

purge

40 mL/min at 25 °C for 11 min

dry purge

2 min

desorption preheat

220 °C

bake

260 °C for 10 min

transfer line/valve temp.

110 °C

column

Equity-1, 30 m x 0.32 mm I.D., 1.0 μm (28057-U)

oven

40 °C (2 min), 5 °C/min to 75 °C, 10 °C/min to 200 °C

inj. temp.

200 °C

detector

FID, 250 °C

carrier gas

helium, 1.4 mL/min constant

injection

20:1 split

liner

0.75 mm I.D. SPME

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