Pairwise hydrogen addition in the selective semihydrogenation of alkynes on silica-supported Cu catalysts.

Pairwise hydrogen addition in the selective semihydrogenation of alkynes on silica-supported Cu catalysts.

Chemical science (2017-04-30)

Oleg G Salnikov, Hsueh-Ju Liu, Alexey Fedorov, Dudari B Burueva, Kirill V Kovtunov, Christophe Copéret, Igor V Koptyug

RESUMEN

Mechanistic insight into the semihydrogenation of 1-butyne and 2-butyne on Cu nanoparticles supported on partially dehydroxylated silica (Cu/SiO

MATERIALES

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Sigma-Aldrich

2-Butyne, 99%