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An isomorphous series of cubic, copper-based triazolyl isophthalate MOFs: linker substitution and adsorption properties.

Inorganic chemistry (2012-07-04)
Jörg Lincke, Daniel Lässig, Merten Kobalz, Jens Bergmann, Marcel Handke, Jens Möllmer, Marcus Lange, Christian Roth, Andreas Möller, Reiner Staudt, Harald Krautscheid
RESUMEN

An isomorphous series of 10 microporous copper-based metal-organic frameworks (MOFs) with the general formulas (∞)(3)[{Cu(3)(μ(3)-OH)(X)}(4){Cu(2)(H(2)O)(2)}(3)(H-R-trz-ia)(12)] (R = H, CH(3), Ph; X(2-) = SO(4)(2-), SeO(4)(2-), 2 NO(3)(2-) (1-8)) and (∞)(3)[{Cu(3)(μ(3)-OH)(X)}(8){Cu(2)(H(2)O)(2)}(6)(H-3py-trz-ia)(24)Cu(6)]X(3) (R = 3py; X(2-) = SO(4)(2-), SeO(4)(2-) (9, 10)) is presented together with the closely related compounds (∞)(3)[Cu(6)(μ(4)-O)(μ(3)-OH)(2)(H-Metrz-ia)(4)][Cu(H(2)O)(6)](NO(3))(2)·10H(2)O (11) and (∞)(3)[Cu(2)(H-3py-trz-ia)(2)(H(2)O)(3)] (12(Cu)), which are obtained under similar reaction conditions. The porosity of the series of cubic MOFs with twf-d topology reaches up to 66%. While the diameters of the spherical pores remain unaffected, adsorption measurements show that the pore volume can be fine-tuned by the substituents of the triazolyl isophthalate ligand and choice of the respective copper salt, that is, copper sulfate, selenate, or nitrate.

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Sigma-Aldrich
Isophthalic acid, 99%
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Número de referencia del producto (SKU)Tamaño de envaseDisponibilidadPrecio
100 mL
1 Fecha estimada de envío 26 de febrero de 2025
EUR 28,80

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