Unexpectedly large binding constants of azulenes with fullerenes.

Unexpectedly large binding constants of azulenes with fullerenes.

Chemical communications (Cambridge, England) (2008-03-01)

A F M Mustafizur Rahman, Sumanta Bhattacharya, Xiaobin Peng, Takahide Kimura, Naoki Komatsu

RESUMEN

In spite of having small pi-conjugation systems, azulenes show large binding constants (10(4)-10(5)) to C(60) and C(70), which are larger than those of monoporphyrins and alternant aromatic hydrocarbons.

MATERIALES

Referencia del producto

Marca

Descripción del producto

A97203

Sigma-Aldrich

Azulene, 99%