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  • Amido-Schiff base derivatives as colorimetric fluoride sensor: Effect of nitro substitution on the sensitivity and color change.

Amido-Schiff base derivatives as colorimetric fluoride sensor: Effect of nitro substitution on the sensitivity and color change.

Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy (2015-05-24)
Soumen Ghosh, Md Akhtarul Alam, Aniruddha Ganguly, Nikhil Guchhait
ABSTRACT

A series of Schiff bases synthesized by the condensation of benzohydrazide and -NO2 substituted benzaldehyde have been used as selective fluoride ion sensor. Test paper coated with these synthetic Schiff bases (test kits) can detect fluoride ion selectively with a drastic color change and detection can be achieved by just using the naked-eye without the help of any optical instrument. Interestingly, the position of -NO2 group in the amido Schiff bases has an effect on the sensitivity as well as on the change of color of species.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Benzaldehyde, SAJ special grade, ≥98.0%
Sigma-Aldrich
Water, for cell biology, sterile ultrafiltered
Sigma-Aldrich
Benzaldehyde, ≥98%, FG, FCC
Sigma-Aldrich
Hydrazine, anhydrous, 98%
Sigma-Aldrich
Benzaldehyde, natural, FCC, FG
Sigma-Aldrich
Tetrabutylammonium fluoride on silica gel, ~1.5 mmol/g (F-)
Sigma-Aldrich
Water, deuterium-depleted, ≤1 ppm (Deuterium oxide)
Sigma-Aldrich
Tetrabutylammonium acetate, 97%
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Tetrabutylammonium acetate, technical, ≥90% (T)
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Water, for embryo transfer, sterile-filtered, BioXtra, suitable for mouse embryo cell culture
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E-Toxate Water, endotoxin, free
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Water, PCR Reagent
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Water, BioPerformance Certified
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Water, Nuclease-Free Water, for Molecular Biology
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Water, sterile-filtered, BioReagent, suitable for cell culture
Sigma-Aldrich
Water, for molecular biology, sterile filtered
Sigma-Aldrich
Benzaldehyde, purified by redistillation, ≥99.5%
Sigma-Aldrich
Tetrabutylammonium phosphate monobasic solution, 1.0 M in H2O
Sigma-Aldrich
Benzaldehyde, ReagentPlus®, ≥99%
Sigma-Aldrich
Benzoic acid, SAJ first grade, ≥99.5%
Sigma-Aldrich
Benzoic acid, SAJ special grade, ≥99.5%
Sigma-Aldrich
Benzoic acid, ≥99.5%, FCC, FG
Sigma-Aldrich
Benzoic acid, natural, ≥99.5%, FCC, FG
Sigma-Aldrich
Tetrabutylammonium chloride, ≥97.0% (NT)
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Tetrabutylammonium nitrate, 97%
Sigma-Aldrich
Tetrabutylammonium acetate solution, 1.0 M in H2O
Sigma-Aldrich
Tetrabutylammonium bromide solution, 50 wt. % in H2O
Sigma-Aldrich
Benzoic acid, puriss. p.a., ACS reagent, reag. Ph. Eur., ≥99.9% (alkalimetric)
Sigma-Aldrich
Tetrabutylammonium fluoride solution, 1.0 M in THF
Sigma-Aldrich
Hydrazine solution, 1.0 M in THF