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Merck

Recent advances in homogeneous nickel catalysis.

Nature (2014-05-16)
Sarah Z Tasker, Eric A Standley, Timothy F Jamison
ABSTRACT

Tremendous advances have been made in nickel catalysis over the past decade. Several key properties of nickel, such as facile oxidative addition and ready access to multiple oxidation states, have allowed the development of a broad range of innovative reactions. In recent years, these properties have been increasingly understood and used to perform transformations long considered exceptionally challenging. Here we discuss some of the most recent and significant developments in homogeneous nickel catalysis, with an emphasis on both synthetic outcome and mechanism.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Nickel, wire, diam. 0.25 mm, ≥99.9%
Sigma-Aldrich
Raney®-Nickel, W.R. Grace and Co. Raney® 3202, slurry, in H2O, active catalyst
Sigma-Aldrich
Nickel, powder, <150 μm, 99.99% trace metals basis
Sigma-Aldrich
Nickel, foil, thickness 0.125 mm, ≥99.9%
Sigma-Aldrich
Nickel, powder, <1 μm, 99.8% trace metals basis
Sigma-Aldrich
Nickel, foil, thickness 0.25 mm, 99.995% trace metals basis
Sigma-Aldrich
Nickel, wire, diam. 0.5 mm, ≥99.99% trace metals basis
Sigma-Aldrich
Raney®-Nickel, W.R. Grace and Co. Raney® 2400, slurry, in H2O, active catalyst
Sigma-Aldrich
Raney®-Nickel, W.R. Grace and Co. Raney® 2800, slurry, in H2O, active catalyst
Sigma-Aldrich
Chloro(4-cyanophenyl)[(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine]nickel(II), ≥95%
Sigma-Aldrich
Chloro(4-cyanophenyl)[(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine]nickel(II)
Sigma-Aldrich
Phenox O-PC A0202, New Iridium, ≥97%
Nickel, foil, 25x25mm, thickness 0.25mm, as rolled, 99.99+%
Nickel, foil, 0.5m coil, thickness 0.3mm, annealed, 99%
Nickel, foil, 10mm disks, thickness 0.025mm, as rolled, 100%
Nickel, foil, 10m coil, thickness 0.3mm, coil width 1mm, as rolled, 99%
Nickel, wire reel, 100m, diameter 0.125mm, hard, 99.98%
Nickel, foil, 0.5m coil, thickness 0.003mm, 99.95%
Nickel, foil, 50x50mm, thickness 0.25mm, as rolled, 99.999%
Nickel, foil, 4mm disks, thickness 0.05mm, 99.9%
Nickel, foil, 10m coil, thickness 0.20mm, coil width 1mm, annealed, 99%
Nickel, tube, 500mm, outside diameter 5.9mm, inside diameter 5.65mm, wall thickness 0.125mm, hard, 99.5%
Nickel, foil, 50x50mm, thickness 0.25mm, annealed, 99.98%
Nickel, foil, 10mm disks, thickness 0.008mm, 99.95%
Nickel, foil, 150x150mm, thickness 0.3mm, as rolled, 99.999%
Nickel, wire reel, 100m, diameter 1.0mm, as drawn, 99%
Nickel, pellets, 100g, max. size 10mm, 99.99+%
Nickel, foil, 0.5m coil, thickness 0.30mm, as rolled, 99.98%
Nickel, foil, 2m coil, thickness 0.3mm, coil width 1mm, annealed, 99%
Nickel, tube, 500mm, outside diameter 4.5mm, inside diameter 3.154mm, wall thickness 0.673mm, hard, 99.5%