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Sigma-Aldrich

Bismuth(III) nitrate pentahydrate

99.999% trace metals basis

Synonym(s):

Bismuth trinitrate pentahydrate

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About This Item

Linear Formula:
Bi(NO3)3 · 5H2O
CAS Number:
10035-06-0
Molecular Weight:
485.07
EC Number:
233-791-8
UNSPSC Code:
12352302
PubChem Substance ID:
24855361
NACRES:
NA.22

Assay

99.999% trace metals basis

form

crystals

reaction suitability

core: bismuth
reagent type: catalyst

bp

75-80 °C (lit.)

mp

30 °C (lit.)

SMILES string

O=[N+](O[Bi](O[N+]([O-])=O)O[N+]([O-])=O)[O-].C

InChI

1S/CH4.Bi.3NO3/c;;3*2-1(3)4/h1H4;;;;/q;+3;3*-1

InChI key

DPLOIMSBRDLLRI-UHFFFAOYSA-N

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Application

An excellent oxidant for a variety of 4-substituted Hantzsch 1,4-dihydropyridines. Convenient reagent for selective oxidation of sufides to sulfoxides.

Pictograms

Flame over circleCorrosion
GHS03,GHS05

Signal Word

Danger

Hazard Statements

H272,H318

Hazard Classifications

Eye Dam. 1 - Ox. Sol. 2

Storage Class Code

5.1B - Oxidizing hazardous materials

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Guojun Han et al.
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Mashraqui, S.H. et al.
Synthetic Communications, 28, 939-939 (1998)
Mashraqui, S.H. Karnik, M.A.
Synthesis, 713-713 (1998)
Na Li et al.
Dalton transactions (Cambridge, England : 2003), 43(36), 13742-13750 (2014-08-12)
The xFe2O3/yBiOCl composites (xFe/yBi, x/y = 0/100, 5/100, 10/100, 20/100, 30/100 and 40/100 molar ratios) are prepared for the first time through an in situ hydrolysis method under hydrothermal conditions. The samples are characterized by X-ray diffraction (XRD), scanning electron
Marcela Luísa Gomes et al.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 20(5), 771-779 (2015-05-02)
Two bismuth(III) porphyrins-5,10,15,20-tetrakis(phenyl)porphyrinatobismuth(III) nitrate, [Bi(III)(TPP)]NO3, and the unprecedent 5,10,15,20-tetrakis(4-carbomethoxyphenyl)porphyrinatobismuth(III) nitrate, [Bi(III)(T4CMPP)]NO3, and two unprecedented antimony(V) porphyrins dichlorido(5,10,15,20-tetrakis(phenyl)porphyrinato)antimony(V) bromide, [Sb(V)(TPP)Cl2]Br, and dibromido(5,10,15,20-tetrakis(4-carbomethoxyphenyl)porphyrinato)antimony(V) bromide, [Sb(V)(T4CMPP)Br2]Br,-were synthesized by reacting the corresponding porphyrin ligand with Bi(NO3)3·5H2O or SbCl3. All compounds were characterized by UV-vis
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