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140066

Sigma-Aldrich

1,3,5-Tribromobenzene

98%

Sinónimos:

1,3,5-Tribromobenzene

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About This Item

Fórmula empírica (notación de Hill):
C6H3Br3
Número de CAS:
626-39-1
Peso molecular:
314.80
Beilstein/REAXYS Number:
1858917
EC Number:
210-947-3
MDL number:
MFCD00000080
UNSPSC Code:
12352100
PubChem Substance ID:
24848449
NACRES:
NA.22

assay

98%

form

powder

bp

271 °C (lit.)

mp

117-121 °C (lit.)

SMILES string

Brc1cc(Br)cc(Br)c1

InChI

1S/C6H3Br3/c7-4-1-5(8)3-6(9)2-4/h1-3H

InChI key

YWDUZLFWHVQCHY-UHFFFAOYSA-N

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General description

  • 1,3,5-Tribromobenzene(TBB) acts as internal standard during derivatization step in determination of cyanide in human plasma and urine by gas chromatography-mass spectrometry.
  • TBB forms molecular complexes of 1:2 stoichiometry with [60]-and [70] fullerenes.
  • TBB reacts with perfluoroalkenylzinc reagent in the presence of Pd(Ph3)4 catalyst to yield a novel trifunctional monomer 1,3,5-tris(α, β, β-trifluorovinyl)benzene.

hcodes

H413

Hazard Classifications

Aquatic Chronic 4

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Lawrence A Ford et al.
Chemical communications (Cambridge, England), (20)(20), 2596-2597 (2003-11-05)
The reaction of the perfluoroalkenylzinc reagent, CF2=CFZnBr, with 1,3,5-tribromobenzene in the presence of a catalytic amount of Pd(Ph3)4 yielded a novel trifunctional monomer 1,3,5-tris(alpha,beta,beta-trifluorovinyl)benzene (1).
S Kage et al.
Journal of forensic sciences, 33(1), 217-222 (1988-01-01)
A sensitive analysis of sulfide in blood was established, using an extractive alkylation technique. Pentafluorobenzyl bromide was used as the alkylating agent, tetradecyldimethylbenzylammonium chloride as the phase-transfer catalyst, and potassium dihydrogenphosphate as the buffer to suppress the formation of sulfide.
Kakali Datta et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 62(1-3), 66-70 (2005-11-01)
By UV-vis spectrophotometric method it has been shown that 1,3,5-tribromobenzene (TBB) forms molecular complexes of 1:2 stoichiometry with [60]- and [70]fullerenes. An isosbestic point could be detected in case of the [70]fullerene complex. The formation constant of the [60]fullerene complex
Guojie Liu et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 877(27), 3054-3058 (2009-09-08)
Cyanide (CN) is a powerful poison and rapidly toxic agent. Because of its wide availability and high toxicity, quantification of CN in blood and urine is frequently required in clinical and forensic practice. We present a sensitive and less time
Y Suzuki et al.
Nucleic acids symposium series, (44)(44), 125-126 (2003-08-09)
We have designed a new type of a DNA dendrimer which has rigid branched structure. The branching molecule was prepared from 1,3,5-tribromobenzene. The dendrimer unit, in which three oligonucleotide-chains, two molecules of T15 and one molecule of A15, linked to
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