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229547

Sigma-Aldrich

Ammonium cerium(IV) nitrate

≥99.99% trace metals basis

Synonym(s):

Ceric ammonium nitrate

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About This Item

Linear Formula:
Ce(NH4)2(NO3)6
CAS Number:
16774-21-3
Molecular Weight:
548.22
EC Number:
240-827-6
MDL number:
MFCD00151121
UNSPSC Code:
12352302
PubChem Substance ID:
24853285
NACRES:
NA.23

Assay

≥99.99% trace metals basis

form

crystalline

reaction suitability

reagent type: oxidant

impurities

≤100.0 ppm Trace Metal Analysis

SMILES string

N.N.[Ce+4].O[N+]([O-])=O.O[N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/Ce.2HNO3.4NO3.2H3N/c;6*2-1(3)4;;/h;2*(H,2,3,4);;;;;2*1H3/q+4;;;4*-1;;

InChI key

WIBGOERAEYJBOT-UHFFFAOYSA-N

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Application

Ammonium cerium(IV) nitrate was used to initiate the graft polymerization of polyacrylic acid with magnetic cation exchange adsorbents, which was used in conjugation with micellar aqueous two-phase systems for protein separation.
Offers a novel route to tartronic acid derivatives via facile oxygenation of malonates.

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Ox. Sol. 2 - Skin Corr. 1B - Skin Sens. 1A

Storage Class Code

5.1B - Oxidizing hazardous materials

WGK

WGK 3

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Protein separation with magnetic adsorbents in micellar aqueous two-phase systems.
Becker JS, et al.
Separation and Purification Technology, 65.1, 46-53 (2009)
Nair, V. et al.
Tetrahedron Letters, 39, 2801-2801 (1998)
D Subhas Bose et al.
Journal of combinatorial chemistry, 12(1), 100-110 (2009-12-17)
An efficient and practical method has been manifested for the diversity-oriented synthesis of quinolines via Friedländer annulation reaction for the generation of a wide range of structurally interesting and pharmacologically significant compounds by using ceric ammonium nitrate as a catalyst
S Sudha et al.
Ultrasonics sonochemistry, 19(5), 994-998 (2012-03-09)
Tetrahydrobenzo[c]xanthenes-11-ones was synthesized by a three component reaction of α-naphthol, aromatic aldehyde and dimedone. Ceric ammonium nitrate acts as a suitable eco-friendly catalyst for this method. Shorter reaction duration, mild reaction condition and low cost make this protocol more effective.
Rasika Tankhiwale et al.
Colloids and surfaces. B, Biointerfaces, 69(2), 164-168 (2009-01-10)
The present work describes ceric ammonium nitrate (CAN) initiated graft copolymerization of acrylamide onto cellulose-based filter paper followed by entrapment of silver nanoparticles. The copolymerization was carried out in aqueous solution, containing 2M acrylamide monomer and 16mM N,N'-methylene bisacrylamide (MB)
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