L3900

2,6-Lutidine

ReagentPlus^®, 98%

• Synonyme(s) : 2,6-Diméthylpyridine
• Formule empirique (notation de Hill): C₇H₉N
• Numéro CAS: 108-48-5
• Poids moléculaire : 107.15
• Beilstein: 105690
• Numéro CE : 203-587-3
• Numéro MDL: MFCD00006345
• Code UNSPSC : 12352005
• ID de substance PubChem : 24896359
• Nomenclature NACRES : NA.22

Propriétés

• Niveau de qualité: 200
• Gamme de produits: ReagentPlus^®
• Essai: 98%
• Forme: liquid
• Indice de réfraction: n20/D 1.497 (lit.)
• pb: 143-145 °C ((lit.)); 143-145 °C (lit.)
• Pf: -6 °C; −6 °C (lit.)
• Densité: 0.92 g/mL at 25 °C ((lit.)); 0.92 g/mL at 25 °C (lit.)
• Chaîne SMILES: CCCCCCCCCCCC(=O)ON1C(=O)CCC1=O; Cc1cccc(C)n1
• InChI: 1S/C16H27NO4/c1-2-3-4-5-6-7-8-9-10-11-16(20)21-17-14(18)12-13-15(17)19/h2-13H2,1H3; 1S/C7H9N/c1-6-4-3-5-7(2)8-6/h3-5H,1-2H3
• Clé InChI: LRKGVVJOUNKTGG-UHFFFAOYSA-N; OISVCGZHLKNMSJ-UHFFFAOYSA-N

Description

Application

2,6-Lutidine can be used as a base for the oxidation of α-CF₃ alcohols to the corresponding carbonyl compounds in the presence of 4-acetamido-2,2,6,6-tetramethylpiperidine-1-oxoammonium tetrafluoroborate (Bobbitt′s salt) as oxidation reagent.
It can be used:

• As a promoter for catalytic asymmetric fluorination of α-cyanophosphonates in the presence of chiral Pd(II)-bisphosphine complexes.
• In combination with tert-butyldimethylsilyl triflate for the protection of tertiary alcohols and unreactive secondary alcohols.
• In combination with triethylsilyl trifluoromethanesulfonate for the conversion of acetals to the corresponding aldehydes in dichloromethane followed by workup in water.

Informations légales

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Informations sur la sécurité

• Pictogrammes: GHS02,GHS07
• Mention d'avertissement: Warning
• Mentions de danger: H226,H302,H315,H319
• Conseils de prudence: P210 - P301 + P312 + P330 - P302 + P352 - P305 + P351 + P338
• Classification des risques: Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2
• Code de la classe de stockage: 3 - Flammable liquids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): 91.4 °F
• Point d'éclair (°C): 33 °C
• Équipement de protection individuelle: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter