Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
262099
Oxychlorure de phosphore(V)
99.999%
Synonyme(s) :
Oxychlorure de phosphore (V), Trichlorure de phosphoryle
About This Item
28 mmHg ( 20 °C)
Produits recommandés
Densité de vapeur
5.3 (vs air)
Niveau de qualité
Pression de vapeur
104 mmHg ( 50 °C)
28 mmHg ( 20 °C)
Essai
99.999%
Forme
liquid
pH
1 (20 °C)
pb
105.8 °C (lit.)
Pf
1.25 °C (lit.)
Densité
1.645 g/mL at 25 °C (lit.)
Groupe fonctionnel
phosphine oxide
Chaîne SMILES
ClP(Cl)(Cl)=O
InChI
1S/Cl3OP/c1-5(2,3)4
Clé InChI
XHXFXVLFKHQFAL-UHFFFAOYSA-N
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Application
- A dehydrating agent in organic synthesis.[1]
- A reagent in the cyclization of substituted aryl amides by Bischler−Napieralski cyclization reaction.[2]
- A precursor for phosphorus diffusion in the p-type silicon solar cells processing.[3]
It can also be used in the Vilsmeier-Haack reaction to synthesize aromatic aldehydes.[4]
À utiliser avec
Mention d'avertissement
Danger
Mentions de danger
Classification des risques
Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1A - STOT RE 1 Inhalation
Organes cibles
Respiratory Tract
Risques supp
Code de la classe de stockage
6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
Classe de danger pour l'eau (WGK)
WGK 1
Point d'éclair (°F)
Not applicable
Point d'éclair (°C)
Not applicable
Équipement de protection individuelle
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdfHelpful?
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