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223891

Sigma-Aldrich

Bismuth(III) oxide

Bismuth(III) oxide
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ReagentPlus®, powder, 10 μm, 99.9% trace metals basis

Synonyme(s) :

Dibismuth trioxide

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About This Item

Formule empirique (notation de Hill):
Bi2O3
Numéro CAS:
1304-76-3
Poids moléculaire :
465.96
Numéro CE :
215-134-7
Numéro MDL:
MFCD00003462
Code UNSPSC :
12352103
ID de substance PubChem :
24853412
Nomenclature NACRES :
NA.23
Le tarif et la disponibilité ne sont pas disponibles actuellement.

Niveau de qualité

200

Gamme de produits

ReagentPlus®

Essai

99.9% trace metals basis

Forme

powder

Pertinence de la réaction

reagent type: catalyst
core: bismuth

Taille des particules

10 μm

Chaîne SMILES 

O=[Bi]O[Bi]=O

InChI

1S/2Bi.3O

Clé InChI

WMWLMWRWZQELOS-UHFFFAOYSA-N

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Description générale

Bismuth (III) oxide is a yellow, monoclinic crystalline powder. It is insoluble in water and hydroxide solutions but dissolves in acids to form bismuth (III) salts. It can be prepared by heating bismuth in air or by heating hydroxides, carbonates or nitrates of bismuth.

Application

General applications of bismuth (III) oxide are:production of optical glasses with high indices of refraction, precursor in the production of other bismuth compounds.
Bismuth (III) oxide is suitable for dental materials to render them opaque to X-rays.
It is used for the synthesis of pure BiFeO3 perovskite nanoparticles,[1] lead free piezoelectric 0.96(Bi0.5Na0.5)TiO3 - 0.04 BaTiO3.

Caractéristiques et avantages

Preparation of new stabilized, oxide ion-conducting, bismuth vanadate phases by a microwave assisted method, from V2O5, Bi2O3 and other solid oxides, was reported. These ceramics show promise in solid oxide fuel cells, water-vapor electrolyzers and oxygen sensors.[2]

Informations légales

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

nwg

Équipement de protection individuelle

dust mask type N95 (US), Eyeshields, Gloves

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Certificats d'analyse (COA)

Lot/Batch Number
0000376257
0000376258
0000358490
0000312795
0000312801

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Consulter la Bibliothèque de documents

Direct mechanosynthesis of pure BiFeO 3 perovskite nanoparticles: reaction mechanism.
Perejon A, et al.
Journal of Material Chemistry C, 1(22), 3551-3562 (2013)
L M Formosa et al.
Dental materials : official publication of the Academy of Dental Materials, 28(5), 584-595 (2012-03-14)
Tricalcium silicate is the major constituent phase in mineral trioxide aggregate (MTA). It is thus postulated that pure tricalcium silicate can replace the Portland cement component of MTA. The aim of this research was to evaluate the microstructure and surface
L M Formosa et al.
International endodontic journal, 45(4), 326-336 (2011-11-03)
To investigate the physical properties of tricalcium silicate (TCS) with and without the addition of a radiopacifier and compare them with that of Portland cement (PC) and radiopaque PC in an mineral trioxide aggregate-like system. Tricalcium silicate, PC and radiopacified
Arun Prakash Periasamy et al.
Talanta, 87, 15-23 (2011-11-22)
In this work, preparation and characterization of a novel nanocomposite containing bismuth oxide (Bi(2)O(3)) nanoparticles and multiwalled carbon nanotubes (MWCNTs) was presented. Powder X-ray diffraction (XRD) studies revealed that as-synthesized Bi(2)O(3) nanoparticles are crystalline and belong to α-phase with monoclinic
Lu You et al.
ACS nano, 6(6), 5388-5394 (2012-05-18)
The novel strain-driven morphotropic phase boundary (MPB) in highly strained BiFeO(3) thin films is characterized by well-ordered mixed phase nanodomains (MPNs). Through scanning probe microscopy and synchrotron X-ray diffraction, eight structural variants of the MPNs are identified. Detailed polarization configurations
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Thermoelectric Performance of Perovskite-type Oxide Materials

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