L512001

sec-Butyl stannatrane

• Sinónimos: 5-(sec-Butyl)-1-aza-5-stannabicyclo[3.3.3]undecane
• Fórmula empírica (notación de Hill): C₁₃H₂₇NSn
• Peso molecular: 316.07
• MDL number: MFCD28009156
• UNSPSC Code: 12352200
• PubChem Substance ID: 329817554

Propiedades

• SMILES string: CC(CC)[Sn]1(CCC2)CCCN2CCC1
• InChI: 1S/C9H18N.C4H9.Sn/c1-4-7-10(8-5-2)9-6-3;1-3-4-2;/h1-9H2;3H,4H2,1-2H3;
• InChI key: QQDZOYQDJQQXLR-UHFFFAOYSA-N

Descripción

Application

Secondary stannatranes are an innovative source of a secondary nucleophile for Pd-catalyzed cross-coupling and have been reported to provide more convenience over alternatives, e.g. boronates, Grignards, etc.

Stereoretentive Pd-catalysed Stille cross-coupling reactions of secondary alkyl azastannatranes and aryl halides.

Other Notes

Please note that Sigma-Aldrich provides this product to early discovery researchers as part of a collection of unique chemicals. Sigma-Aldrich does not collect analytical data for this product. Buyer assumes responsibility to confirm product identity and/or purity. All sales are final.

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Información de seguridad

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable