460990
Sodium trans-hyponitrite hydrate
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About This Item
Fórmula lineal:
Na2N2O2 · xH2O
Número de CAS:
Peso molecular:
105.99 (anhydrous basis)
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.22
Productos recomendados
form
solid
storage temp.
2-8°C
SMILES string
[Na+].[Na+].[H]O[H].[O-]\N=N\[O-]
InChI
1S/H2N2O2.2Na.H2O/c3-1-2-4;;;/h(H,1,4)(H,2,3);;;1H2/q;2*+1;/p-2
InChI key
MNTPJDLNJKAOKU-UHFFFAOYSA-L
Application
Precursor to tert-butyl hyponitrite which was employed in the low-temperature thermal generation of tert-butoxy radicals.
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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T C Hollocher et al.
The Journal of biological chemistry, 255(11), 5027-5030 (1980-06-10)
13N- and 15N-labeling experiments were carried out with Paracoccus denitrificans, grown anaerobically on nitrate, to determine whether hyponitrite might be an obligatory intermediate in denitrification and a precursor of nitrous oxide. From experiments designed to trap [13N]- or [15N,15N]hyponitrite by
An umpolung approach to cis-hyponitrite complexes.
Navamoney Arulsamy et al.
Angewandte Chemie (International ed. in English), 41(13), 2371-2373 (2002-08-31)
Hyun Joo et al.
The journal of physical chemistry. A, 109(7), 1420-1429 (2006-07-13)
In the reaction of F2PBr, F2P(O)Br, (C6F5)2PBr, (CH3)2P(S)Br, and (CH3)2P(O)Cl with silver hyponitrite (AgON=NOAg), nitrous oxide (N2O) and mu-oxo phosphorus species were obtained in all cases rather than the plausible hyponitrite alternative. Theoretical calculations of the geometries and expected decomposition
Nan Xu et al.
Journal of the American Chemical Society, 131(7), 2460-2461 (2009-02-05)
The coupling of two nitric oxide (NO) molecules in heme active sites is an important contributor to the conversion of NO to nitrous oxide (N(2)O) by heme-containing enzymes. Several formulations for the presumed heme-Fe{N(2)O(2)}(n-) intermediates have been proposed previously, however
The structure of the hyponitrite species in a heme Fe-Cu binuclear center.
Constantinos Varotsis et al.
Angewandte Chemie (International ed. in English), 46(13), 2210-2214 (2007-02-14)
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