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Merck

159239

Sigma-Aldrich

2-Bromoanisole

97%

Sinónimos:

1-Bromo-2-methoxybenzene

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About This Item

Fórmula lineal:
BrC6H4OCH3
Número de CAS:
Peso molecular:
187.03
Beilstein/REAXYS Number:
1859996
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

assay

97%

form

liquid

refractive index

n20/D 1.573 (lit.)

bp

223 °C (lit.)

mp

2 °C (lit.)

density

1.502 g/mL at 25 °C (lit.)

SMILES string

COc1ccccc1Br

InChI

1S/C7H7BrO/c1-9-7-5-3-2-4-6(7)8/h2-5H,1H3

InChI key

HTDQSWDEWGSAMN-UHFFFAOYSA-N

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General description

Diffusion coefficients of 2-bromoanisole at infinite dilution in supercritical carbon dioxide has been evaluated by Taylor-Aris chromatographic technique.

Application

2-Bromoanisole was used in the synthesis of unsymmetrically substituted biphenyl compounds. It was also used in the preparation of the family of exo-[n.m.n.m]metacyclophanes (n,m > or = 3).

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Aquatic Chronic 3 - Eye Irrit. 2 - Skin Irrit. 2

Storage Class

10 - Combustible liquids

wgk_germany

WGK 1

flash_point_f

208.4 °F - closed cup

flash_point_c

98 °C - closed cup

ppe

Eyeshields, Gloves


Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Diffusion coefficients of 2-fluoroanisole, 2-bromoanisole, allylbenzene and 1, 3-divinylbenzene at infinite dilution in supercritical carbon dioxide
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Fluid Phase Equilibria, 260(2), 279-286 (2007)
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The Journal of organic chemistry, 65(17), 5185-5196 (2000-09-19)
A general strategy for the preparation of the family of exo-[n.m.n.m]metacyclophanes (n,m > or = 3) in 6-steps (starting from 2-bromoanisole) that utilizes a [2 + 2] approach to furnish the exo-metacyclophane ring in good to moderate yield is described.
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