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Sigma-Aldrich

Tris(trimethylsilyl) phosphate

new
greener alternative

≥99.0%, anhydrous, battery grade

Sinonimo/i:

Phosphoric acid tris(trimethylsilyl ester), TMSP, TMSPA

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About This Item

Formula condensata:
[(CH3)3SiO]3P(O)
Numero CAS:
Peso molecolare:
314.54
Beilstein:
1794624
Numero MDL:
Codice UNSPSC:
12352005

Grado

battery grade

Livello qualitativo

Descrizione

Application: Battery manufacturing

Saggio

≥99.0%

Forma fisica

(colorless liquid)

Caratteristiche più verdi

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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Impurezze

 ppm H2O≤500
≤500 ppm H2O

Indice di rifrazione

n20/D 1.409 (lit.)

P. eboll.

228-229 °C/720 mmHg (lit.)
228-229 °C

Punto di fusione

3-4 °C (lit.)
3-4 °C

Densità

0.945 g/mL at 25 °C (lit.)

applicazioni

battery manufacturing

Categoria alternativa più verde

Stringa SMILE

C[Si](C)(C)OP(=O)(O[Si](C)(C)C)O[Si](C)(C)C

InChI

1S/C9H27O4PSi3/c1-15(2,3)11-14(10,12-16(4,5)6)13-17(7,8)9/h1-9H3
QJMMCGKXBZVAEI-UHFFFAOYSA-N

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Descrizione generale

Tris(trimethylsilyl) borate (TMSB) is an electron-deficient organoborate compound. It is a colorless liquid that that is miscible with many organic solvents, including the linear and cyclic carbonates used in battery applications. Our battery grade TMSB is differentiated by its high purity and low trace water content to ensure consistent and reliable performance in batteries.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Click here for more information.

Applicazioni

Tris(trimethylsilyl) borate has a wide range of applications in various industries, including battery manufacturing, where it is used as an electrolyte additive, particularly in high-voltage lithium-ion batteries. TMSB is a cathode-film-forming additive that forms a thin protective coating called a solid-electrolyte interface (SEI) on the surface of the cathode. Adding TMSB to the electrolyte formulation, even at low concentrations of 0.5 wt.%, noticeably improves capacity retention for NMC, LMO, and LMNO cathodes. TMSB also is shown to reduce the flammability of the electrolyte and improve the thermal stability of LiPF6-based electrolytes at elevated temperatures.TMSB also has catalytic properties, which make it useful in organic synthesis reactions and as a reagent in the manufacturing of pharmaceuticals and other chemicals.

Prodotti correlati

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Descrizione
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Pittogrammi

FlameExclamation mark

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

Organi bersaglio

Respiratory system

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 2

Punto d’infiammabilità (°F)

55.4 °F - closed cup

Punto d’infiammabilità (°C)

13 °C - closed cup


Certificati d'analisi (COA)

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Tris(trimethylsilyl)borate as an electrolyte additive for improving interfacial stability of high voltage layered lithium-rich oxide cathode/carbonate-based electrolyte
Li J, et al.
Journal of Power Sources, 285, 360-366 (2015)
Effect of tris(trimethylsilyl)borate on the high voltage capacity retention of LiNi0.5Co0.2Mn0.3O2/graphite cells
Zuo X, et al
Journal of Power Sources, 229, 308-312 (2013)
Tris(trimethylsilyl) borate as an electrolyte additive to improve the cyclability of LiMn2O4 cathode for lithium-ion battery
Liu Y, et al.
Journal of Power Sources, 221, 90-96 (2013)
Importance of Reduction and Oxidation Stability of High Voltage Electrolytes and Additives
Delp Samuel A, et.al
Electrochimica Acta, 498-510, 209-209 (2016)

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