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393436

Sigma-Aldrich

Tris(2,6-dimethoxyphenyl)phosphine

98%

Sinonimo/i:

DMPP

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About This Item

Formula condensata:
[(CH3O)2C6H3]3P
Numero CAS:
85417-41-0
Peso molecolare:
442.44
Numero MDL:
MFCD00192558
Codice UNSPSC:
12352112
ID PubChem:
24864518

Saggio

98%

Forma fisica

powder

Impiego in reazioni chimiche

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Cross Couplings

Punto di fusione

145-147 °C (lit.)

Gruppo funzionale

phosphine

Stringa SMILE

COc1cccc(OC)c1P(c2c(OC)cccc2OC)c3c(OC)cccc3OC

InChI

1S/C24H27O6P/c1-25-16-10-7-11-17(26-2)22(16)31(23-18(27-3)12-8-13-19(23)28-4)24-20(29-5)14-9-15-21(24)30-6/h7-15H,1-6H3
CMLWFCUAXGSMBB-UHFFFAOYSA-N

Applicazioni

Catalyst for:
  • Preparation of chiral building blocks via hydroalkynylation reactions or ynolates
  • Three-component aza-Morita-Baylis-Hillman reactions (aza-MBH)
  • Atom-economic synthesis of nitrogen heterocycles and ynenoates from alkynes
  • Oxycylizations of allendiols
  • Enantioselective aldol reactions
  • Pd-mediated cross-coupling, Pd- and Cu-mediated benzannulation reactions and copper-mediated dimerization reactions

Pittogrammi

Exclamation mark
GHS07

Avvertenze

Warning

Indicazioni di pericolo

H315,H319,H335

Classi di pericolo

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Organi bersaglio

Respiratory system

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

dust mask type N95 (US), Eyeshields, Gloves

Certificati d'analisi (COA)

Cerca il Certificati d'analisi (COA) digitando il numero di lotto/batch corrispondente. I numeri di lotto o di batch sono stampati sull'etichetta dei prodotti dopo la parola ‘Lotto’ o ‘Batch’.

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