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Key Documents

295485

Sigma-Aldrich

Bromomethane

≥99%

Sinonimo/i:

Methyl bromide

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About This Item

Formula empirica (notazione di Hill):
CH3Br
Numero CAS:
Peso molecolare:
94.94
Beilstein:
1209223
Numero CE:
Numero MDL:
Codice UNSPSC:
12352100
ID PubChem:
NACRES:
NA.22

Densità del vapore

3.3 (20 °C, vs air)

Livello qualitativo

Tensione di vapore

1420 mmHg ( 20 °C)

Saggio

≥99%

Temp. autoaccensione

996 °F

Limite di esplosione

~16 %

P. eboll.

4 °C (lit.)

Punto di fusione

−94 °C (lit.)

Solubilità

water: soluble

Densità

3.3 g/mL at 25 °C (lit.)

Stringa SMILE

CBr

InChI

1S/CH3Br/c1-2/h1H3
GZUXJHMPEANEGY-UHFFFAOYSA-N

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Descrizione generale

Bromomethane (methyl bromide) is the most effective soil fumigant for killing plant pests, its use is being phased out because its emissions from soil can lead to stratospheric ozone depletion. The bimolecular nucleophilic substitution (S(N)2) reaction of methyl bromide and OH- in aqueous solution has been investigated using a multilayered-representation quantum mechanical and molecular mechanics methodology.

Applicazioni

Please view www.aldrich.com/epaods regarding the EPA′s request for application information of Ozone Depleting Substances

Prodotti consigliati

Brass control valve Z146943 or either of brass regulators Z146706 and Z146714 is recommended.

Raccomandato

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Regolatore

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Avvertenze

Danger

Classi di pericolo

Acute Tox. 2 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Eye Irrit. 2 - Muta. 2 - Ozone 1 - Press. Gas Liquefied gas - Skin Irrit. 2 - STOT RE 2 - STOT SE 3

Organi bersaglio

Central nervous system, Respiratory system

Codice della classe di stoccaggio

2A - Gases

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

<-22.0 °F - liquid

Punto d’infiammabilità (°C)

< -30 °C - liquid

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves


Certificati d'analisi (COA)

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Richeng Xuan et al.
Environmental science & technology, 44(23), 9080-9085 (2010-11-10)
Despite generally being considered the most effective soil fumigant, methyl bromide (MeBr) use is being phased out because its emissions from soil can lead to stratospheric ozone depletion. However, a large amount is still currently used due to Critical Use
Alan V Barak et al.
Journal of economic entomology, 104(1), 69-74 (2011-03-17)
Ash (Fraxinus spp.) logs, infested with fully developed, cold-acclimated larval and prepupal emerald ash borer, Agrilus planipennis Fairmaire (Coleoptera: Buprestidae), were fumigated with methyl bromide (MeBr) at 4.4 and 10.0 degrees C for 24 h. Concentrations X time dosages of
Marcus Schortemeyer et al.
Journal of economic entomology, 104(3), 717-731 (2011-07-09)
Following the increasing international phasing out of methyl bromide for quarantine purposes, the development of alternative treatments for timber pests becomes imperative. The international accreditation of new quarantine treatments requires verification standards that give confidence in the effectiveness of a
Lygia T Budnik et al.
Environmental health : a global access science source, 11, 5-5 (2012-01-31)
Although ozone-depleting methyl bromide was destined for phase-out by 2005, it is still widely applied as a consequence of various critical-use-exemptions and mandatory international regulations aiming to restrict the spread of pests and alien species (e.g. in globalized transport and
Paul E Stromberg et al.
Clinical toxicology (Philadelphia, Pa.), 51(3), 182-185 (2013-03-12)
Methyl bromide is a halogenated aliphatic hydrocarbon that exists as a colorless gas or a volatile liquid. Methyl bromide historically had been used in fire extinguishers but is more commonly used as a gas fumigant for soil-borne diseases and pests.

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